| Identification | Back Directory | [Name]
4,4,5,5-TetraMethyl-2-(3-triphenylen-2-yl-phenyl)-[1,3,2]dioxaborolane | [CAS]
890042-13-4 | [Synonyms]
(Triphenylen-2-yl)boronic acid pinacol ester
(Triphenylene-2-yl) boronic acid pinacol ester
1,3, 2-Dioxaborane-4,4,5,5-tetramethyl-2-(2-triphenylene)
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)triphenylene
4,4,5,5-TetraMethyl-2-triphenylen-2-yl-[1,3,2]dioxaborolane
1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(2-triphenylenyl)-
4,4,5,5-TetraMethyl-2-triphenylen-2-yl-[1,3,2]dioxaborolane
(TPE)
4,4,5,5-TetraMethyl-2-(3-triphenylen-2-yl-phenyl)-[1,3,2]dioxaborolane | [Molecular Formula]
C24H23BO2 | [MDL Number]
MFCD26401844 | [MOL File]
890042-13-4.mol | [Molecular Weight]
354.249 |
| Chemical Properties | Back Directory | [Melting point ]
174.0 to 178.0 °C | [Boiling point ]
544.9±19.0 °C(Predicted) | [density ]
1.16±0.1 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature |
| Hazard Information | Back Directory | [Uses]
4,4,5,5-TetraMethyl-2-(3-triphenylen-2-yl-phenyl)-[1,3,2]dioxaborolane can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly for laboratory research and development Process and chemical production process. | [Synthesis]
In a nitrogen atmosphere, 100 g (326 mmol) of 2-bromotriphenylene was dissolved in dimethylformamide(Pinacolato diboron) 99.2 (manufactured by Wako Pure Chemical Industries, Ltd.) was dissolved in 1,000 mL of dimethylformamide (DMF)G (391 mmol) and 1,1'-bis (diphenylphosphine) ferrocene) dichloropalladium (II) (1,1-Bis (diphenylphosphine) ferrocene) dichloropalladium (II)) 2.66 g (3.26 mmol) and potassium acetate 80 g (815 mmol) of potassium acetate were added and the mixture was refluxed by heating at 150 DEG C for 5 hours. After completing the reaction,Water was added to the solution, the mixture was filtered, and then dried in a vacuum oven. The thus obtained residue was purified by flash column chromatographyTo obtain 113 g (98%) of the compound I-1. HRMS (70 eV, EI +): m / z Calcd for C24H23BO2: 354.1791, found |
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