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ChemicalBook--->CAS DataBase List--->88404-25-5

88404-25-5

88404-25-5 Structure

88404-25-5 Structure
IdentificationMore
[Name]

4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN
[CAS]

88404-25-5
[Synonyms]

4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN
4-(BROMOMETHYL)-6,7-DIMETHOXYCOUMARIN, 9 7%
4-(Bromomethyl)-6,7-dimethoxycoumarine
4-Bromomethyl-6,7-dimethoxycoumarin [for HPLC Labeling]
4-(Bromomethyl)-6,7-dimethoxy-2H-1-benzopyran-2-one
[Molecular Formula]

C12H11BrO4
[MDL Number]

MFCD00011570
[Molecular Weight]

299.12
[MOL File]

88404-25-5.mol
Chemical PropertiesBack Directory
[Appearance]

Light Greenish-Yellow Powder
[Melting point ]

212-216 °C(lit.)
[density ]

1.6176 (rough estimate)
[refractive index ]

1.4490 (estimate)
[storage temp. ]

Refrigerator
[solubility ]

Soluble in acetonitrile, dichloromethane, N,N-dimethylformamide, methanol
[color ]

Yellow crystals or powder
[Water Solubility ]

Insoluble in water.
[Usage]

A fluorescent labeling reagent for the reversed-phase HPLC separation and detection of carboxylic acids
[λmax]

348 nm (MeOH)
[BRN ]

4750487
[Biological Applications]

Analyzing bile acid; anticancer agents; identifying bacteria; identifying/measuring lauric acid metabolites; measuring cyclosporine; studying/monitoring early stages of protein folding;treating gastrointestinal diseases; derivatization reagent for carboxylic acids; as a substrate for measuring lauric acid hydroxylase activity
[Major Application]

Electrostatic imaging process; resists; printed circuit boards; semiconductor devices
[CAS DataBase Reference]

88404-25-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xn,C
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

1759
[WGK Germany ]

3
[F ]

21
[Hazard Note ]

Corrosive
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29322090
Hazard InformationBack Directory
[Chemical Properties]

Light Greenish-Yellow Powder
[Uses]

4-Bromomethyl-6,7-dimethoxycoumarin was used as fluorescent labeling reagent for the reversed-phase HPLC separation and detection of carboxylic acids. It was also used as derivatization reagent:
  • for quantitation of clofibric, bezafibric and fenofibric acids in liver by liquid chromatography
  • in determination of the concentration of tripeptide glutathione by matrix-assisted laser desorption ionization time-of-flight mass spectrometry
  • for determination of carboxylic acids in chromatographic detection
[Uses]

4-Bromomethyl-6,7-dimethoxycoumarin is used as fluorescent labeling reagent for the reversed-phase HPLC separation and detection of carboxylic acids. It is also used as derivatization reagent: for quantitation of clofibric, bezafibric and fenofibric acids in liver by liquid chromatography, in determination of the concentration of tripeptide glutathione by matrix-assisted laser desorption ionization time-of-flight mass spectrometry and for determination of carboxylic acids in chromatographic detection.
[Uses]

A fluorescent labeling reagent for the reversed-phase HPLC separation and detection of carboxylic acids
Spectrum DetailBack Directory
[Spectrum Detail]

4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN(88404-25-5)IR
4-BROMOMETHYL-6,7-DIMETHOXYCOUMARIN(88404-25-5)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

4-Bromomethyl-6,7-dimethoxycoumarin, 95%(88404-25-5)
[Sigma Aldrich]

88404-25-5(sigmaaldrich)
[TCI AMERICA]

4-Bromomethyl-6,7-dimethoxycoumarin  [for HPLC Labeling],>98.0%(LC)(88404-25-5)
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