Identification | More | [Name]
3-METHOXYBENZYL BROMIDE | [CAS]
874-98-6 | [Synonyms]
1-BROMOMETHYL-3-METHOXYBENZENE 3-METHOXYBENZYL BROMIDE 3-(Bromomethyl)anisole,1-(Bromomethyl)-3-methoxybenzene 3-Methoxybenzyl bromide 98% m-Methoxybenzylbromide 3-Methoxybenzyl bromide ,98% (3-Methoxyphenyl)bromomethane 3-(Bromomethyl)anisole | [Molecular Formula]
C8H9BrO | [MDL Number]
MFCD00216590 | [Molecular Weight]
201.06 | [MOL File]
874-98-6.mol |
Chemical Properties | Back Directory | [Appearance]
Colorless liquid | [Boiling point ]
152 °C(lit.) | [density ]
1.436 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.575(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
-20°C Freezer | [form ]
Liquid | [color ]
Clear colorless to light yellow | [Detection Methods]
HPLC,GC,NMR | [CAS DataBase Reference]
874-98-6(CAS DataBase Reference) | [Storage Precautions]
Store under nitrogen |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S27:Take off immediately all contaminated clothing . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [Hazard Note ]
Corrosive | [HS Code ]
29049090 |
Hazard Information | Back Directory | [Chemical Properties]
Colorless liquid | [Uses]
3-Methoxybenzyl bromide (1-bromomethyl-3-methoxybenzene) may be used in the diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives. It may be used in the synthesis of the following:
- 6-(3-methoxyphenyl)-hexane-2,4-dione
- N-(3-methoxybenzyl)-N-(1-methyl-1-phenylethyl)-amine
- 2-(3-methoxybenzyl)-3-[(1R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-(3S)-2-thionia-bicyclo [2.2.1]- heptane tetrafluoroborate
- 1-(3-methoxybenzyl)-5-(1-methyl-1H-imidazol-5-yl)-1H-1,2,3-triazole
| [Uses]
3-Methoxybenzyl bromide is a benzyl bromide derivative used as a benzyl group rearrangement catalyst.
| [General Description]
3-Methoxybenzyl bromide is a benzyl bromide derivative. |
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