Identification | More | [Name]
7-Ethoxy-4-methyl-2H-chromen-2-one | [CAS]
87-05-8 | [Synonyms]
4-METHYL-7-ETHOXYCOUMARIN 7-ETHOXY-4-METHYL-2H-CHROMEN-2-ONE 7-ETHOXY-4-METHYLCOUMARIN ETHYL 4-METHYLUMBELLIFERYL ETHER METHYL-7-ETHOXYCOUMARIN, 4- TIMTEC-BB SBB010011 2H-1-Benzopyran-2-one, 7-ethoxy-4-methyl- 7-ethoxy-4-methyl-2h-1-benzopyran-2-on Coumarin, 7-ethoxy-4-methyl- 7-ETHOXY-4-METHYLCOUMARIN, FOR FLUORESCE NCE Maraniol 7-Ethoxy-4-methylcoumarin 98% METHYL-7-ETHOXYCOUMARIN, 4-(SG) 7-ETHOXY-4-METHYLCOUMARIN WITH GC 4-Methyl-7-ethoxy-2H-1-benzopyran-2-one 7-Ethoxy-4-methyl-2H-1-benzopyran-2-one Morlin | [EINECS(EC#)]
201-721-5 | [Molecular Formula]
C12H12O3 | [MDL Number]
MFCD00016971 | [Molecular Weight]
204.22 | [MOL File]
87-05-8.mol |
Hazard Information | Back Directory | [Chemical Properties]
White solid; walnut odor. Slightly soluble in alcohol. | [Definition]
ChEBI: 7-Ethoxy-4-methyl-2H-1-benzopyran-2-one is a member of coumarins. | [General Description]
7-Ethoxy-4-methylcoumarin (EtOMC), also known as ethyl 4-methylumbelliferyl ether, is a coumarin derivative. Its standard molar energy of combustion is ?5888.0 ± 3.2kJ·mol?1 and standard molar enthalpy of formation in the crystalline phase is ?545.4 ± 3.6kJ·mol?1.EtOMC can be prepared by reacting methyl acetoacetate with 3-ethoxyphenol in the presence of boron trifluoride dihydrate.The fluorescence quenching of EtOMC is more effective in the presence 4-hydroxy-TEMPO (4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl). | [Synthesis]
Prod.: 1) from Diketene plus Resorcinol with sulfuric
acid to produce 4-Methyl-7-hydroxy -
coumarin. Ethylation produces subject
material. 2) from Resorcinol plus Ethylacetoacetate,
followed by Ethylation. |
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