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ChemicalBook--->CAS DataBase List--->79319-85-0

79319-85-0

79319-85-0 Structure

79319-85-0 Structure
IdentificationBack Directory
[Name]

BISMERTHIAZOL
[CAS]

79319-85-0
[Synonyms]

MBAMT
Saikuzuo
chuanhua018
Teqingshuang
Yeqingshuang
BISMERTHIAZOL
bismerthianol
Bismerthiazol PESTANAL
N,N’-Methylene-bis(2-amino-5-mercapto-1,3,4-thiadiazole
N,N’-Methylenebis(2-amino-5-mercapto-1,3,4-thiadiazole)
4-thiadiazole-2(3h)-thione,5,5’-(methylenediimino)bis-3
3,4-Thiadiazole-2(3H)-thione,5,5’-(methylenediimino)bis-1
n,n’-methylene-bis(2-amino-5-sulfhydryl-1,3,4-thiadiazole)
1,3,4-Thiadiazole-2(3H)-thione, 5,5'-(methylenediimino)bis-
5,5'-(methanediyldiimino)bis(1,3,4-thiadiazole-2(3H)-thione)
5,5'-(Methylenebis(azanediyl))bis(1,3,4-thiadiazole-2(3H)-thione)
Bismerthiazol,N,N′-Methylene-bis(2-amino-5-sulfhydryl-1,3,4-thiadiazole)
[Molecular Formula]

C5H6N6S4
[MDL Number]

MFCD01681864
[MOL File]

79319-85-0.mol
[Molecular Weight]

278.4
Chemical PropertiesBack Directory
[Boiling point ]

415.4±55.0 °C(Predicted)
[density ]

2.12±0.1 g/cm3(Predicted)
[storage temp. ]

2-8°C
[pka]

7.20±0.20(Predicted)
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[RTECS ]

XI4816000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Formaldehyde-->Carbon disulfide-->Ammonium thiocyanate-->Hydrazine sulfate-->2-Mercapto-5-methyl-1,3,4-thiadiazole-->thiosemicarbazide-->Hydrazodicarbothioamide
Hazard InformationBack Directory
[Chemical Properties]

Pure product is white rectangular columnar or light yellow loose powder, mp189~191℃ (industrial product mp172~174℃), decomposition temperature 200℃, easily soluble in dimethylformamide, pyridine, dimethyl sulfoxide, etc. Soluble in methanol, ethanol, acetone, insoluble in benzene, chloroform and water.
[Uses]

Bismerthiazol is a high-efficiency, low-toxicity, and low-residue fungicide for the control of bacterial blight in early, middle and late rice seedlings and Honda.
[Synthesis]

Bismerthiazol can be prepared by the methods:Put 180kg of hydrazine sulfate, a small amount of catalyst, and 165kg of ammonium thiocyanate into the reactor, heat to reflux, cool, filter, wash with water, and suction filter to obtain dithiourea.
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