天堂网亚洲,天天操天天搞,91视频高清,菠萝蜜视频在线观看入口,美女视频性感美女视频,95丝袜美女视频国产,超高清美女视频图片

ChemicalBook--->CAS DataBase List--->23564-05-8

23564-05-8

23564-05-8 Structure

23564-05-8 Structure
IdentificationBack Directory
[Name]

Thiophanate-methyl
[CAS]

23564-05-8
[Synonyms]

DO
ROKO
nf44
ditek
f6385
SIGMA
COVER
3336G
trevin
easout
td1771
pei190
pelt14
pelt-44
fungo50
metoben
enovitm
CYCOSIN
AIMTHYL
TOPSIN M
Topxin-M
frumidor
fungitox
caligran
sipcasan
sipcavit
neotopsin
cercobinm
bas32500f
Midothane
MILDOTHANE
CEKUFANATO
Cercobin-M
sipcaplant
topsinnf-44
enovitsuper
LABILITE(R)
FUNGITOX(R)
TOPSIN M(R)
CERCOBINM-70
methyltopsin
enovitmethyl
thiophanatem
CERCOBIN-M(R)
topsinwpmethyl
cercobinmethyl
tiofanatemetile
methylthiofanate
methylthiophanate
THIOPHANAT-METHYL
THIOPHANATE-METHYL
O,O-Dimethyl analog
THIOPHANATE,METHYLESTER
Thiophanate methyl W.P.
topsinturfandornamentals
Thiophanate-methyl Standard
THIOPHANATE-METHYL, 1GM, NEAT
THIOPHANATE-METHYL PESTANAL, 250 MG
Thiophanate-methyl 1g [23564-05-8]
thiophanate-methyl (bsi,iso,ansi,jmaf)
1,2-BIS(METHOXYCARBONYLTHIOUEIDO) BENZENE
1,2-bis(methoxycarbonylthioureido)benzene
o-bis(3-methoxycarbonyl-2-thioureido)benzene
1,2-di-(3-Methoxy-carbonyl-2-thioureido)benzene
1,2-BIS(3-METHOXYCARBANYL-2-THIOUREIDO) BENZENE
1,2-Bis(3-(methoxycarbonyl)-2-thioureido)benzene
DIMETHYL-4,4'-O-PHENYLENEBIS-(3-THIOALLOPHANATE)
4,4’-o-phenylenebis(3-thio-allophanicacidimethylester
4,4'-o-Phenylenebis[3-thioallophanic Acid DiMethyl Ester
DIMETHYL((1,2-PHENYLENE)BIS(IMINOCARBONOTHIOYL))BISCARBA.
DIMETHYL([1,2-PHENYLENE]BIS(IMINOCARBONOTHIOYL))BIS(CARBAMATE)
1,2-DI(3-METHOXYCARBONYL-2-THIOUREIDO)BENZENE /THIOPHANATE METHYL
Thiophanate-methyl ,1,2-di-(3-methoxycarbonyl-2-thioureido)benzene
(1,2-phenylenebis(iminocarbonothioyl))bis-carbamicacidimethylester
[1,2-phenylenebis(iminocarbonothioyl)]bis-carbamicacidimethylester
[1,2-Phenylenebis(iminocarbonothioyl)]bis[carbamicacid]dimethylester
Carbamicacid,[1,2-phenylenebis(iminocarbonothioyl)]bis-,dimethylester
thiophanate-methyl (ISO) 1,2-di-(3-methoxycarbonyl-2-thioureido)benzene
Methyl N-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate
N,N'-[1,2-Phenylenebis(iMinocarbonothioyl)]biscarbaMic Acid C,C'-DiMethyl Ester
[EINECS(EC#)]

245-740-7
[Molecular Formula]

C12H14N4O4S2
[MDL Number]

MFCD00055294
[MOL File]

23564-05-8.mol
[Molecular Weight]

342.39
Chemical PropertiesBack Directory
[Appearance]

Methyl thiophanate is a colorless crystals, prisms or light brown powder.
[Melting point ]

172°C
[density ]

1.4542 (rough estimate)
[vapor pressure ]

<1.3 x 10-5 Pa (25 °C)
[refractive index ]

1.6000 (estimate)
[storage temp. ]

0-6°C
[solubility ]

DMF: 30 mg/mL; DMSO: 30 mg/mL
[form ]

neat
[pka]

7.28
[color ]

White to off-white
[Stability:]

Stable. Incompatible with strong oxidizing agents, alkalies, copper salts.
[Water Solubility ]

<0.1 g/100 mL at 20 ºC
[Merck ]

13,9427
[BRN ]

937942
[LogP]

1.4 at 25℃
[EPA Substance Registry System]

Carbamic acid, [1,2-phenylenebis(iminocarbonothioyl)] bis-, dimethyl ester(23564-05-8)
Hazard InformationBack Directory
[Chemical Properties]

colourless crystals, or white or light brown powder
[Uses]

Thiophanate-Methyl is a systematic fungicide of the thiophanate class. Thiophanate-Methyl is commonly used in agriculture to protect against powdery mildew, rot and other fungal diseases in fruits, ve getables and other crops.
[Definition]

ChEBI: A member of the class of thioureas that is the dimethyl ester of (1,2-phenylenedicarbamothioyl)biscarbamic acid. A fungicide effective against a broad spectrum of diseases in fruit, vegetables, turf and other crops including eyespot, scab, powdery mildew a d grey mould.
[Uses]

Systemic fungicide.
[General Description]

Colorless crystals or light brown powder.
[Air & Water Reactions]

Insoluble in water.
[Reactivity Profile]

Thiophanate-methyl is incompatible with strong acids and bases, and with strong reducing agents such as hydrides. Produces flammable gaseous hydrogen with active metals or nitrides. Incompatible with strong oxidizing acids, peroxides. Incompatible with alkaline material. Forms complexes with copper salts .
[Fire Hazard]

Flash point data for Thiophanate-methyl are not available. Thiophanate-methyl is probably combustible.
[Potential Exposure]

Methyl thiophanate is thiocarbamate ester, used in the synthesis of polymers and in agriculture as pesticides, soil fumigants, and seed disinfectants.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Shampoo hair. Speed in removing material from skin is of extreme importance. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN2771 Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
[Incompatibilities]

Thiocarbamate esters are combustible; dust may form explosive mixture with air. Decomposes163℃Thiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of thiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithio carbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of thiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates are incompatible with acids, peroxides, and acid halides.
[Waste Disposal]

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
[Flammability and Explosibility]

Notclassified
[Agricultural Uses]

Fungicide: Thiophanate-methyl is a systemic fungicide used to control a broad spectrum of fungal diseases on fruits, vegetables, turf and ornamentals, including shade trees, and diseases in the field, nurseries, and in greenhouses. Note: Do not confuse with thiophanate-ethyl (CAS: 23564-06-9), which is not currently registered for use in the U.S. Registered for use in EU countries. Registered for use in the U.S.
[Trade name]

BASF® 32500 F; BASF® 32500 Fungicide; CERCOBIN®; CLEARY® 3336; CONSYST®; DITEK®[C]; DOMAIN®; DOUSAN®[C]; ENOVIT®; EVOLVE®; FANATE®; FUNGITOX®; FUNGO®; MILDOTHANE® Turf Liquid; NEOTOPSIN®; NF- 35®; NF-44®; NSC 170810®; PELT®; PRO-TURF®; SIPCAVIT®; SNARE®; SPECTRO®; SYSTEC®; SYSTEMIC® FUNGICIDE; TD 1771®; TOPSIN®; TOPSIN-WP METHYL®; 3336 TURF FUNGICIDE®; ZYBAN®
[Carcinogenicity]

Those long-term studies evaluated a variety of toxicity end points including carcinogenicity. Both benomyl and carbendazim were weak carcinogens in some in vivo studies. Rats of the SpDxAug strain were fed 80, 400, and 2000 ppm for 2 years and no evidence for an increase in tumors was seen. In carcinogenicity studies in mice with carbendazim, similar liver tumor finding were found in CD-1 or Swiss strains. On the other hand, no evidence of tumors was seen in a similar study conducted using the NMRKf mouse strain, a strain that has a low incidence of spontaneous tumors.
[Metabolic pathway]

Thiophanate methyl degradation in water (hydrolytic/ photolysis), soils, plants and animals follows a common pathway that involves the initial conversion into methyl benzimidazol-2-ylcarbamate (carbendazim). Prior to benzimidazole ring formation, at least one side chain undergoes an oxidative desulfuration reaction and partial hydrolysis (even to the substituted aniline). Once formed, carbendazim is degraded primarily via an oxidative mechanism (in animals) or through hydrolysis to 2-aminobenzimidazole (in soils). Possible metabolism pathways of thiophanate methyl are depicted in Scheme 1.
[Degradation]

Thiophanate methyl (1) is susceptible to alkaline hydrolysis. The principal degradation product is carbendazim (2). Thiophanate methyl degraded slowly in water (pH 7-7.4, Noguchi et al., 1971), and in fruit juice (grape homogenate, Shiga et al., 1985) to primarily carbendazim, but also to 1-(3- methoxycarbony1thioureido)-2-(3-methoxycarbony1ureido)benzene (3) and dimethyl 4,4'-(o-phenylene)bis(allophanate) (4). Thiophanate methyl underwent photolysis in aqueous solution to carbendazim (DT50 <1 day) when illuminated with UV light (254 nm) or natural sunlight. A similar photolytic transformation occurred on moist cotton foliage, although no photolysis occurred when thiophanate methyl was exposed as a dry film to light (Buchenauer et al., 1973). Thiophanate methyl on wet filter paper decomposed in sunlight to yield carbendazim and small amounts of compounds 3 and 4 (Ono and Tohyama, 1982).
Safety DataBack Directory
[Hazard Codes ]

Xn;N,N,Xn
[Risk Statements ]

20-43-50/53-68
[Safety Statements ]

36/37-46-60-61
[RIDADR ]

UN 3077
[WGK Germany ]

2
[RTECS ]

BA3675000
[HS Code ]

29309090
[Hazardous Substances Data]

23564-05-8(Hazardous Substances Data)
[Toxicity]

LD50 in rats, mice, guinea pigs, rabbits (g/kg): 3.40, 6.64, 3.64, 2.27 orally (Hashimoto)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Methanol-->o-Phenylenediamine-->PHOSGENE-->Sodium thiocyanate-->Methyl chloroformate-->ISOTHIOCYANATE, POLYMER-BOUND, 200-400-->METHYL THIOCYANOFORMATE-->Methoxycarbonyl isothiocyanate
[Preparation Products]

Thiram+Thiophanate-methyl W.P.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Thiophanate-methyl (23564-05-8).msds
Questions And AnswerBack Directory
[Description]

Thiophanate methyl is a member of benzimidazole and a systemic fungicide with protective and curative activity against a broad spectrum of fungal diseases including leaf spots, blotches, blights, fruit spots, rots, sooty mould, scabs, bulb/corn/tuber decays, blossom blights, powdery mildews, certain rusts, and common soil borne crown and root rots. It is used on a variety of tree, vine, root crops, canola, and wheat, as well as on lawns and ornamentals. Thiophanate methyl is absorbed by the roots and leaves. Thiophanate-methyl has a low mammalian toxicity. But, it is an irritant and a skin sensitizer. It may also be mutagen. Moderate toxicity of thiophanate methyl is observed for aquatic organisms and earthworms. In EU, thiophanate methyl is approved to control fungal diseases on crops, while in Australia it is not registered for use on food-producing species, while it is only for the control of soil-borne diseases of ornamentals plants. For application, Thiophanate-methyl is formulated into wettable powders containing 50 and 70% active ingredient.
[References]

  1. https://apvma.gov.au
  2. https://www.epa.gov
  3. https://sitem.herts.ac.uk
  4. http://www.inchem.org
  5. Terry R Roberts, David H Hutson, Philip W Lee, Peter H Nicholls, and Jack R Plimmer, Metabolic Pathways of Agrochemicals: Part 2: Insecticides and Fungicides, 1999, ISBN 978-0-85404-499-3
Spectrum DetailBack Directory
[Spectrum Detail]

Thiophanate-methyl(23564-05-8)1HNMR
23564-05-8 suppliers list
Company Name: Hebei Mojin Biotechnology Co., Ltd
Tel: +86 13288715578 +8613288715578 , +8613288715578
Website: http://www.mojinchemical.com
Company Name: Qingdao Trust Agri Chemical Co.,Ltd
Tel: +8613573296305 , +8613573296305
Website: www.qdtrustagri.com/
Company Name: Hebei Weibang Biotechnology Co., Ltd
Tel: +8617732866630 , +8617732866630
Website: www.weibangbio.com
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: +86-0551-65418679 +8618949832763 , +8618949832763
Website: www.tnjchem.com
Company Name: career henan chemical co
Tel: +86-0371-86658258 +8613203830695 , +8613203830695
Website: www.coreychem.com/
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 18871490254
Website: www.hubeijusheng.com
Company Name: Shandong chuangyingchemical Co., Ltd.
Tel: 18853181302
Website: www.approvedhomemanagement.com/ShowSupplierProductsList103425/0.htm
Company Name: Chongqing Chemdad Co., Ltd
Tel: +86-023-6139-8061 +86-86-13650506873 , +86-86-13650506873
Website: http://www.chemdad.com/
Company Name: CONIER CHEM AND PHARMA LIMITED
Tel: +8618523575427 , +8618523575427
Website: http://www.conier.com/
Company Name: Shaanxi Dideu Medichem Co. Ltd
Tel: +86-29-87569266 15319487004 , 15319487004
Website: http://www.approvedhomemanagement.com/manufacturer/shaanxi-dideu-medichem-220/
Company Name: Zhengzhou Alfa Chemical Co.,Ltd
Tel: +8618530059196 , +8618530059196
Website: http://www.approvedhomemanagement.com/manufacturer/zhengzhou-alfa-chemical-276/
Company Name: TargetMol Chemicals Inc.
Tel: +1-781-999-5354 +1-00000000000 , +1-00000000000
Website: https://www.targetmol.com/
Company Name: Hubei Ipure Biology Co., Ltd
Tel: +8613367258412 , +8613367258412
Website: www.ipurechemical.com
Company Name: Longyan Tianhua Biological Technology Co., Ltd
Tel: 0086 18039857276 18039857276 , 18039857276
Website: tianhuaapi.en.alibaba.com
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: +86-0551-65418671 +8618949823763 , +8618949823763
Website: www.tnjchem.com
Company Name: HONG KONG IPURE BIOLOGY CO.,LIMITED
Tel: 86 18062405514 18062405514 , 18062405514
Website: www.approvedhomemanagement.com/ShowSupplierProductsList1523002/0_EN.htm
Company Name: ANHUI WITOP BIOTECH CO., LTD
Tel: +8615255079626 , +8615255079626
Website: www.approvedhomemanagement.com/showsupplierproductslist418627/0_en.htm
Company Name: Xi'an MC Biotech, Co., Ltd.
Tel: 029-89275612 +8618991951683 , +8618991951683
Website: www.approvedhomemanagement.com/ShowSupplierProductsList1759320/0.htm
Tags:23564-05-8 Related Product Information
530-62-1 143390-89-0 109-57-9 10605-21-7 1861-32-1 148-79-8 6320-03-2 624-49-7 75-18-3 96-33-3 74223-64-6 616-38-6 77-78-1 67-68-5 23564-06-9 99-76-3 1330-20-7 68-12-2