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ChemicalBook--->CAS DataBase List--->7536-55-2

7536-55-2

7536-55-2 Structure

7536-55-2 Structure
IdentificationMore
[Name]

BOC-L-Asparagine
[CAS]

7536-55-2
[Synonyms]

BOC-ASN
BOC-ASN-OH
BOC-ASPARAGINE
BOC-L-ASN
BOC-L-ASN-OH
BOC-L-ASPARAGINE
BOC-L-ASPARAGINE-OH
N2-[(1,1-Dimethylethoxy)carbonyl]-L-asparagine
NALPHA-BOC-L-ASPARAGINE
N-ALPHA-T-BOC-L-ASPARAGINE
N-ALPHA-T-BUTOXYCARBONYL-L-ASPARAGINE
N-(ALPHA)-TERT-BUTOXYCARBONYL-L-ASPARAGINE
N-ALPHA-TERT-BUTYLOXYCARBONYL-L-ASPARAGINE
N-BOC-L-ASPARAGINE
N-T-BOC-L-ASPARAGINE
N-T-BUTOXYCARBONYL-L-ASPARAGINE
N-TERT-BUTOXYCARBONYL-L-ASPARAGINE
TBOC-L-ASPARAGINE
T-BUTYLOXYCARBONYL-L-ASPARAGINE
n2-[(1,1-dimethylethoxy)carbonyl]-l-asparagin
[EINECS(EC#)]

231-405-2
[Molecular Formula]

C9H16N2O5
[MDL Number]

MFCD00038152
[Molecular Weight]

232.23
[MOL File]

7536-55-2.mol
Chemical PropertiesBack Directory
[Appearance]

WHITE AMORPHOUS POWDER
[Melting point ]

175 °C (dec.)(lit.)
[Boiling point ]

374.39°C (rough estimate)
[density ]

1.2896 (rough estimate)
[refractive index ]

-7 ° (C=1, DMF)
[Fp ]

245°C
[storage temp. ]

−20°C
[form ]

Powder or Crystalline Powder
[pka]

3.79±0.10(Predicted)
[color ]

White
[optical activity]

[α]20/D 7.8±0.5°, c = 2% in DMF
[Detection Methods]

T,NMR,Rotation
[BRN ]

1977963
[CAS DataBase Reference]

7536-55-2(CAS DataBase Reference)
[EPA Substance Registry System]

7536-55-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

IRRITANT
[HS Code ]

29241990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

L-Asparagine-->L-Asparagine, N,N2-bis[(1,1-dimethylethoxy)carbonyl]--->T -BUTYL-P-NITROPHENYL CARBONATE-->CARBONIC ACID TERT-BUTYL 2,4,5-TRICHLOROPHENYL ESTER-->BOC-ASP-OH-->Carbonofluoridic acid, 1,1-dimethylethyl ester-->Di-tert-butyl dicarbonate-->tert-butyl azidoformate-->2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile
[Preparation Products]

BOC-BETA-CYANO-ALA-OH-->BOC-DAP(Z)-OH DCHA-->N-Boc-N'-xanthyl-L-asparagine-->4-Nitrophenol-->(R)-Methyl 4-aMino-2-((tert-butoxycarbonyl)aMino)-4-oxobutanoate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Boc-Asn-OH(7536-55-2).msds
Hazard InformationBack Directory
[Chemical Properties]

WHITE AMORPHOUS POWDER
[Uses]

Nα-Boc-L-asparagine is an N-Boc-protected form of L-Asparagine (A790005). L-Asparagine was first isolated by Robiquet and Vauquelin from asparagus juice (a high source of L-asparagine). L-Asparagine is often incorporated into proteins, and is a basis for some cancer therapies as certain cancerous cells require L-asparagine for growth.
[Definition]

ChEBI: The Nalpha-t-butoxycarbonyl derivative of L-asparagine
Spectrum DetailBack Directory
[Spectrum Detail]

BOC-L-Asparagine(7536-55-2)MS
BOC-L-Asparagine(7536-55-2)1HNMR
BOC-L-Asparagine(7536-55-2)13CNMR
BOC-L-Asparagine(7536-55-2)IR1
BOC-L-Asparagine(7536-55-2)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

N(alpha)-Boc-L-asparagine, 98+%(7536-55-2)
[Sigma Aldrich]

7536-55-2(sigmaaldrich)
[TCI AMERICA]

Nalpha-(tert-Butoxycarbonyl)-L-asparagine,>98.0%(T)(7536-55-2)
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