| Identification | More | [Name]
8-Methylquinoline | [CAS]
611-32-5 | [Synonyms]
0-Toluquinoline
8-METHYLQUINOLINE
O-TOLUQUINOLINE
8-methyl-quinolin
8-Methylquinoline,98+%
8-Methyl
8-methyquinoline
8-Methylquinoline, 97+%
8-Methylquinoline ,99% | [EINECS(EC#)]
210-264-0 | [Molecular Formula]
C10H9N | [MDL Number]
MFCD00006810 | [Molecular Weight]
143.19 | [MOL File]
611-32-5.mol |
| Chemical Properties | Back Directory | [Appearance]
clear yellow liquid | [Melting point ]
-80 °C | [Boiling point ]
245 °C | [density ]
1.052 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.614(lit.)
| [Fp ]
221 °F
| [storage temp. ]
Room Temperature | [solubility ]
Chloroform, Methanol | [form ]
Liquid | [pka]
5.03±0.17(Predicted) | [color ]
Clear yellow | [Specific Gravity]
1.052 | [Water Solubility ]
0.1-0.5 g/100 mL at 17 ºC | [Detection Methods]
GC,NMR | [BRN ]
111340 | [InChIKey]
JRLTTZUODKEYDH-UHFFFAOYSA-N | [CAS DataBase Reference]
611-32-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Quinoline, 8-methyl-(611-32-5) | [EPA Substance Registry System]
611-32-5(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R68:Possible risk of irreversible effects.
R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
VC0562000
| [TSCA ]
T | [HazardClass ]
IRRITANT | [HS Code ]
29334900 |
| Hazard Information | Back Directory | [General Description]
Yellow liquid or oil. | [Reactivity Profile]
8-METHYLQUINOLINE(611-32-5) may be sensitive to exposure to light. May react vigorously with strong oxidizing agents and strong acids . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. | [Air & Water Reactions]
Slightly soluble in water. | [Fire Hazard]
This chemical is combustible. | [Chemical Properties]
clear yellow liquid | [Uses]
8-Methylquinoline has been used in preparation of osmium chloridophosphine complexes, as quinoline carbene tautomers.Tumorigenic potential of 8-methylquinoline has been evaluated in newborn CD-1 mice and Sprague-Dawley rats. | [Definition]
ChEBI: A methylquinoline carrying a methyl substituent at position 8. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 45, p. 1514, 1980 DOI: 10.1021/jo01296a035 | [Purification Methods]
Purify it as for 2-methylquinoline. The phosphate and picrate have m 158o and m 201o, respectively. [Beilstein 20 III/IV 3500, 20/7 V 405.] |
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