| Identification | More | [Name]
Methyl 2-iodobenzoate | [CAS]
610-97-9 | [Synonyms]
2-IODOBENZOIC ACID METHYL ESTER
BENZOIC ACID, 2-IODO-, METHYL ESTER
IBM
METHYL 2-IODOBENZOATE
METHYL O-IODOBENZOATE
O-IODOBENZOIC ACID METHYL ESTER
RARECHEM AL BF 0562
2-iodo-benzoicacimethylester
Benzoic acid, o-iodo-, methyl ester
2-Iodobenzoate
2-IODOBENZOIC AICD METHYLESTER
Methyl2-Iodobenzoate(2-IodobenzoicAcidMethylEster)
2-IodobenzoicAcidMethylEsterC8H7IO2
4-Methyl 2-Iodobenzoate (2-Iodobenzoic Acid Methyl Ester) C8H7Io2
Methyl2-iodobenzoate,98%
Methyl 2-iodobenzoate, 99+%
Methy1
2-(Methoxycarbonyl)-1-iodobenzene
methyl iodobenzoate | [EINECS(EC#)]
210-243-6 | [Molecular Formula]
C8H7IO2 | [MDL Number]
MFCD00016351 | [Molecular Weight]
262.04 | [MOL File]
610-97-9.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR YELLOW LIQUID | [Melting point ]
64°C | [Boiling point ]
149-150 °C/10 mmHg (lit.) | [density ]
1.784 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.604(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform, Ethyl Acetate (Slightly), Methanol | [form ]
Crystalling or Flaky Powder | [color ]
White | [Water Solubility ]
INSOLUBLE | [Sensitive ]
Light Sensitive | [Detection Methods]
GC,NMR | [BRN ]
2206859 | [Stability:]
Light Sensitive | [InChIKey]
BXXLTVBTDZXPTN-UHFFFAOYSA-N | [CAS DataBase Reference]
610-97-9(CAS DataBase Reference) | [NIST Chemistry Reference]
Methyl-2-iodobenzoate(610-97-9) | [EPA Substance Registry System]
610-97-9(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [TSCA ]
T | [HazardClass ]
IRRITANT | [HS Code ]
29163900 |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR YELLOW LIQUID | [Uses]
Methyl 2-iodobenzoate may be used in the preparation of:
- N-substituted 4-methylene-3,4-dihydro-1(2H)-isoquinolin-1-ones
- methyl diphenylacetylene-2-carboxylate
- methyl 2-heptynylphenylbenzoate
- (E)-2-[3-[3-[2-(7-chloro-2-quinolinyl)ethenyl]phenyl]-3-oxopropyl]benzoic acid methyl ester
- 4-(2-carbomethoxyphenyl)-3-(1-methylethoxy)cyclobut-3-ene-1,2-dione
- 3-(2-carbomethoxyphenyl)-4-methylcyclobuten-3-ene-1,2-dione 2-(ethylene acetal)
| [Synthesis Reference(s)]
Journal of the American Chemical Society, 93, p. 4845, 1971 DOI: 10.1021/ja00748a030 | [General Description]
Methyl 2-iodobenzoate can be prepared from 2-iodobenzoic acid via esterification. It undergoes cobalt-catalyzed cyclization with aldehydes to form phthalide derivatives. The microbial dihydroxylation of methyl 2-iodobenzoate forms a nonracemic iodocyclohexene carboxylate intermediate. This intermediate forms the precursor for preparing kibdelone C. |
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