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ChemicalBook--->CAS DataBase List--->604-53-5

604-53-5

604-53-5 Structure

604-53-5 Structure
IdentificationMore
[Name]

1,1'-BINAPHTHYL
[CAS]

604-53-5
[Synonyms]

1,1'-BINAPHTHALENE
1,1'-BINAPHTHYL
1,1'-DINAPHTHYL
ALPHA,ALPHA'-BINAPHTHYL
1,1’-Binaphthyl(formB)
1,1'-Binaphtyl
alpha,alpha'-Dinaphthylene
Di-alpha-naphthol
[EINECS(EC#)]

210-070-6
[Molecular Formula]

C20H14
[MDL Number]

MFCD00041740
[Molecular Weight]

254.33
[MOL File]

604-53-5.mol
Chemical PropertiesBack Directory
[Appearance]

Brown powder
[Melting point ]

143-146 °C
[Boiling point ]

360 °C
[density ]

1,3 g/cm3
[refractive index ]

1.6292 (estimate)
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Powder
[color ]

Brown
[CAS DataBase Reference]

604-53-5(CAS DataBase Reference)
[EPA Substance Registry System]

Safety DataBack Directory
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
[TSCA ]

Yes
[HS Code ]

29029090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1-(4-Bromophenyl)-naphthlene-->4,4'-Dibromobiphenyl-->1-Iodonaphthalene-->1-Bromo-4-iodobenzene
[Preparation Products]

the BINAP-Rh^<+^> complex
Hazard InformationBack Directory
[Chemical Properties]

Brown powder
[Purification Methods]

Purify 1,1’-binaphthyl through a silica gel column with Me2CO/*C6H6 [or Al2O3 with 10% *C6H6/pet ether (b 30-60o)] and recrystallise it from EtOH, pentane, or slow evaporation of *C6H6, Me2CO or Et2O solutions. Half life ~10hours at 25o in various solvents. [Wilson & Pincock J Am Chem Soc 97 1474 1975, Akimoto & Yamada Tetrahedron 27 5999 1971, Beilstein 5 I 358, 5 II 642, 5 III 2465, 5 IV 2634.]
Spectrum DetailBack Directory
[Spectrum Detail]

1,1'-BINAPHTHYL(604-53-5)MS
1,1'-BINAPHTHYL(604-53-5)1HNMR
1,1'-BINAPHTHYL(604-53-5)13CNMR
1,1'-BINAPHTHYL(604-53-5)IR1
1,1'-BINAPHTHYL(604-53-5)IR2
1,1'-BINAPHTHYL(604-53-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

[Sigma Aldrich]

604-53-5(sigmaaldrich)
[TCI AMERICA]

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