| Identification | More | [Name]
1,1-Cyclopropanedicarboxylic acid | [CAS]
598-10-7 | [Synonyms]
1,1-CYCLOPROPANEDICARBOXYLIC ACID
CYCLOPROPANE-1,1-DICARBOXYLIC ACID
RARECHEM AL BO 0836
1,1-CyclopropanedicarboxylicAcid,97%
Cycloprpopane-1,1-Dicarboxylic
Cyclopropane-1,1-dicarboxylic acid 97%
1,1-cyclopropanedicarboxylate
1-Carboxycyclopropanecarboxylic acid | [EINECS(EC#)]
209-917-2 | [Molecular Formula]
C5H6O4 | [MDL Number]
MFCD00013727 | [Molecular Weight]
130.1 | [MOL File]
598-10-7.mol |
| Chemical Properties | Back Directory | [Appearance]
white to almost white crystalline powder | [Melting point ]
134-136 °C(lit.)
| [Boiling point ]
200.75°C (rough estimate) | [density ]
1.3985 (rough estimate) | [refractive index ]
1.5800 (estimate) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
methanol: soluble1g/10 mL, clear, colorless | [form ]
powder to crystal | [pka]
1.82(at 25℃) | [color ]
White to Almost white | [Water Solubility ]
Soluble | [BRN ]
1864823 | [InChI]
InChI=1S/C5H6O4/c6-3(7)5(1-2-5)4(8)9/h1-2H2,(H,6,7)(H,8,9) | [InChIKey]
FDKLLWKMYAMLIF-UHFFFAOYSA-N | [SMILES]
C1(C(O)=O)(C(O)=O)CC1 | [CAS DataBase Reference]
598-10-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,C | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29172090 |
| Hazard Information | Back Directory | [Chemical Properties]
white to almost white crystalline powder | [Uses]
1,1-Cyclopropanedicarboxylic acid is used to prepare spiro-cyclopropyl metallocycles.1
| [General Description]
Cyclopropane-1,1-dicarboxylic acid is a dicarboxylic acid. Cyclopropane-1,1-dicarboxylic acid, an inhibitor of 1-aminocyclopropane-1-carboxylic acid oxidase, was quantitated in Lycopersicum esculentum by HPLC-electrospray tandem mass spectrometry. Crystal and molecular structure of cyclopropane-1,1-dicarboxylic acid has been reported. | [Purification Methods]
Recrystallise the di-acid from CHCl3, EtOAc or *C6H6/Et2O/pet ether. It forms a monohydrate. [Nicolet & Satler J Am Chem Soc 49 2070 1927, Beilstein 9 II 512, 9 III 3795.] |
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