| Identification | Back Directory | [Name]
Diacetone-D-glucose | [CAS]
582-52-5 | [Synonyms]
NSC 1223
GLUCOFURANOSE
DIACETONEGLUCOSE
Diacetin Glucose
A-D-GLUCOFURANOSE
Diacetone-D-Glucos
Glucose diacetonide
DIACETONE-D-GLUCOSE
Glucose bisacetonide
DIACETONE-ALPHA-D-GLC
D-GLUCOSE DIACETONIDE
DIACETONE-ALPHA-D-GLUCOSE
Diacetone-D-glucose, 98+%
1,2:5,6-Di-O-isopropylidene-
DIISOPROPYLIDENEGLUCOFURANOSE
1,2,5,6-DIISOPROPYLIDENE-D-GLUCOSE
1,2:5,6-DIISOPROPYLIDENE-D-GLUCOSE
Di-O-isopropylidene-a-D-glucofuranose
1,2:5,6-Di-O-isopropylidene-D-glucose
1,2:5,6-Di-isopropylidene-glucofuranose
1.2.5.6-Diisopropylene-a-D-glucofuranose
(-)-1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUC
1,2,5,6-DI-O-ISO-PROPYLIDENEGLUCOFURANOSE
1,2;5,6-DI-O-ISOPROPYLIDENE-D-GLUCOFURANOSE
1,2:5,6-DIISOPROPYLENE-ALPHA-D-GLUCOFURANOSE
D-Glucose diacetonide, Diacetone-D-glucose
1,2,5,6-Di-O-isopropylidene-|-L-glucofuranose
5,6-Di-O-isopropylidene-alpha-D-glucofuranose
1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE
1,2:5,6-di-o-isopropylidene-à-d-glucofuranose
1,2:5,6-Di-O-isopropylidene-a-L-glucofuranose
5:6-di-o-isopropylidene-1:alpha-d-glucofuranos
DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE, 1,2,5,6-
1,2:5,6-DI-O-ISOPROPYLDENE-ALPHA-D-GLUCOFURANOSE
1:2,5:6-di-o-isopropyliden-alpha-d-glucofuranose
1,2:5,6-DI-O-ISOPROPYLIDENE-ALFA-D-GLUCOFURANOSE
1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE,98%
1,2,5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE
1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE
1-O,2-O:5-O,6-O-Diisopropylidene-α-D-glucofuranose
1,2:5,6-O-DI-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE
1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE
1,2:5,6-Bis-O-(1-Methylethylidene)-α-D-glucofuranose
1,2:5,6-Bis-O-(1-Methylethylidene)-a-D-Glucofuranose
1-O,2-O:5-O,6-O-Bis(isopropylidene)-α-D-glucofuranose
(-)-1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE
a-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-
1,2:5,6-bis-o-(1-methylethylidene)-alpha-d-glucofuranos
1-O,2-O:5-O,6-O-Bis(1-methylethylidene)-α-D-glucofuranose
.alpha.-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-
(-)-1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose for synthesis
1,2,5,6-Di-O-isopropylidene-alpha-D-glucofuranose (Diacetone-D-g
Diacetone-D-Glucose/1,2:5,6-Di-O-Isopropylidene-Alpha-D-Glucofuranose
1,2,5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE (DIACETONE-D-GLUCOSE)
5-(2,2-Dimethyl-(1,3)dioxolan-4-yl)-2,2-dimethyl-4H-furo(2,3-d)(1,3)dioxol-6-ol
1,2,5,6-diisopropylidene-D-glucose, D-Glucose diacetonide, Diacetone-D-glucose
5-(2,2-DIMETHYL-[1,3]DIOXOLAN-4-YL)-2,2-DIMETHYL-TETRAHYDRO-FURO[2,3-D][1,3]DIOXOLE
1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose~1,2:5,6-Diisopropylidene-D-glucose
(3aR,5S,6S,6aR)-5-((R)-2,2-DiMethyl-1,3-dioxolan-4-yl)-2,2-diMethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ol
(3aR,3aα,6aα)-5α-[(4R)-2,2-Dimethyl-1,3-dioxolane-4-yl]-2,2-dimethyltetrahydrofuro[2,3-d]-1,3-dioxole-6α-ol
1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose, 1,2:5,6-Diisopropylidene-D-glucose, D-glucose diacetonide
(3aR,5S,6S,6aR)-5-[(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[4,5-d][1,3]dioxol-6-ol | [EINECS(EC#)]
209-486-0 | [Molecular Formula]
C12H20O6 | [MDL Number]
MFCD00005544 | [MOL File]
582-52-5.mol | [Molecular Weight]
260.28 |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
110-111 °C(lit.)
| [alpha ]
-11 º (c=5, EtOH) | [Boiling point ]
323.54°C (rough estimate) | [density ]
1.1432 (rough estimate) | [refractive index ]
-18.5 ° (C=5, H2O) | [storage temp. ]
−20°C
| [solubility ]
Chloroform (Slightly), Methanol (Slightly), Water (Slightly, Sonicated) | [form ]
Powder | [pka]
13.15±0.60(Predicted) | [color ]
White to yellow | [optical activity]
[α]20/D 18°, c = 1% in H2O | [Water Solubility ]
slightly soluble | [Merck ]
14,2965 | [BRN ]
84386 | [InChIKey]
KEJGAYKWRDILTF-YENDLIOYSA-N | [EPA Substance Registry System]
.alpha.-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)- (582-52-5) |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
It is mainly used in biochemical reaction and used as medicine intermediate. It is used in synthesize for below products: L-gulose;1,2:5,6-Di-O-isopropylidene-a-D-gulofuranose; Alllose; ;1,2:5,6-Double-O-Isopropylidene-3-C-(1-Methoxycarbonyl)Ethide-alfa-D-Furanose) ;1,2:5,6-Di-O-isopropylidene-a-D-ribo-hexofuranose-3-ulose;6-deoxy idose. | [Purification Methods]
Diacetone-D-glucose crystallises from Et2O, (needles), pet ether or *C6H6 and sublimes in vacuo. It is soluble in 7 volumes of H2O and 200 volumes of pet ether at their boiling points. The solubility in H2O at 17.5o is 4.3%. It precipitates from aqueous solutions on basification with NaOH. [Schmid & Karrer Helv Chim Acta 32 1371 1949, Fischer & Rund Chem Ber 49 90, 93 1916, IR: Kuhn Anal Chem 22 276 1950, Beilstein 19/12 V 318.] |
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