Identification | Back Directory | [Name]
1,4-EPOXY-1,4-DIHYDRONAPHTHALENE | [CAS]
573-57-9 | [Synonyms]
NSC 101863 Benzooxanorbornadiene 7-OXABENZONORBORNADIENE 1,4-Dihydronaphthalene-1,4-oxide 1,4-EPOXY-1,4-DIHYDRONAPHTHALENE 1,4-DIHYDRO-1,4-EPOXYNAPHTHALENE 1,4-Epoxynaphthalene,1,4-dihydro- 1,4-Dihydronaphthalene-1,4-epoxide 1,3-Etheno-1,3-dihydroisobenzofuran 1,4-EPOXY-1,4-DIHYDRONAPHTHALENE 99% 1,4-Epoxy-1,4-dihydronaphthalene,99% 1,4-Dihydronaphthalene-1,4-endo-oxide (1S)-1β,4β-Epoxy-1,4-dihydronaphthalene 11-Oxatricyclo[6.2.1.02,7]undeca-2(7),3,5,9-tetrene 11-Oxatricyclo[6.2.1.02,7]undecane-2(7),3,5,9-tetrene (1β,8β)-11-Oxatricyclo[6.2.1.02,7]undeca-2,4,6,9-tetrene (1R,8S)-11-Oxatricyclo[6.2.1.02,7]undeca-2,4,6,9-tetrene (1R,8S)-11-Oxatricyclo[6.2.1.02,7]undeca-2(7),3,5,9-tetrene | [Molecular Formula]
C10H8O | [MDL Number]
MFCD00167584 | [MOL File]
573-57-9.mol | [Molecular Weight]
144.17 |
Chemical Properties | Back Directory | [Appearance]
white to yellow crystalline solid | [Melting point ]
54-56 °C(lit.)
| [Boiling point ]
241℃ | [density ]
1.207 | [refractive index ]
1.5598 (estimate) | [Fp ]
93 °C
| [form ]
powder to crystal | [color ]
White to Almost white |
Hazard Information | Back Directory | [Chemical Properties]
white to yellow crystalline solid | [Synthesis Reference(s)]
Canadian Journal of Chemistry, 43, p. 1599, 1965 DOI: 10.1139/v65-211 Chemistry Letters, 12, p. 1211, 1983 | [Purification Methods]
Dissolve it in Et2O, wash it with H2O, dry it over K2CO3, filter, evaporate and dry the residue at 15mm, then recrystallise it from pet ether (b 40-60o), dry it at 25o/0.005mm and sublime it (sublimes slowly at room temperature)[Wittig & Pohmer Chem Ber 89 1334 1956, Gilman & Gorsich J Am Chem Soc 79 2625 1957]. [Beilstein 17 III/IV 548.] |
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