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ChemicalBook--->CAS DataBase List--->55285-14-8

55285-14-8

55285-14-8 Structure

55285-14-8 Structure
IdentificationMore
[Name]

Carbosulfan
[CAS]

55285-14-8
[Synonyms]

2,3-DIHYDRO-2,2-DIMETHYL-7-BENZOFURANYL)-N-DIBUTYLAMINTHIO-N-METHYL-CARBAMATE
2,3-DIHYDRO-2,2-DIMETHYLBENZOFURAN-7-YL (DIBUTYLAMINOTHIO)METHYLCARBAMATE
2,3-DIHYDRO-2,2-DIMETYL-7-BENZOFURANYL-[(DIBUTYLAMINO)THIO]METHYLCARBAMATE
ADVANTAGE(R)
AGROSTAR
AMITAGE
BRIGHT
CARBOSHELL
CARBOSULFAN
GAZELLE(R)
MARSHAL
MARSHAL(R)
POSSE(R)
((dibutylamino)thio)methylcarbamicacid,2,2-dimethyl-2,3-dihydro-7-benzofura
2,2-Dimethyl-2,3-dihydro-1-benzofuran-7-yl (dibutylamino)sulfanyl(methyl)carbamate
2,3-dihydro-2,2-dimethyl-7-benzofuranyl((dibutylamino)thio)methylcarbamate
2,3-dihydro-2,2-dimethyl-7-benzofuranyl(di-n-butylaminosulfenyl)methylcarbam
2,3-Dihydro-2,2-dimethyl-7-benzofuranyl[(dibutylamino)thio]methyl carbamate
Advantage
Carbamic acid, [(dibutylamino)thio]methyl-, 2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester
[EINECS(EC#)]

259-565-9
[Molecular Formula]

C20H32N2O3S
[MDL Number]

MFCD00143930
[Molecular Weight]

380.54
[MOL File]

55285-14-8.mol
Chemical PropertiesBack Directory
[Appearance]

Orange-yellow thick liquid.
[Melting point ]

<25 °C
[Boiling point ]

approximate 126℃
[density ]

1.0560
[vapor pressure ]

3.1 x 10-5 Pa (20 °C)
[refractive index ]

1.6360 (estimate)
[Fp ]

96 °C
[storage temp. ]

0-6°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

neat
[pka]

3.15±0.70(Predicted)
[Water Solubility ]

0.3 mg l-1 (25 °C)
[color ]

Light brown to brown
[Merck ]

13,1836
[LogP]

6.050 (est)
[CAS DataBase Reference]

55285-14-8(CAS DataBase Reference)
[NIST Chemistry Reference]

Carbamic acid, [(dibutylamino)thio]methyl-, 2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester(55285-14-8)
[EPA Substance Registry System]

55285-14-8(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T;N,N,T
[Risk Statements ]

R23/25:Toxic by inhalation and if swallowed .
R43:May cause sensitization by skin contact.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S24:Avoid contact with skin .
S37:Wear suitable gloves .
S38:In case of insufficient ventilation, wear suitable respiratory equipment .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 2810
[WGK Germany ]

3
[RTECS ]

EZ3815000
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[Toxicity]

LD50 in male, female rats (mg/kg): 250, 185 orally; in male, female rabbits (mg/kg): >2000, >2000 dermally; in pheasant, mallard, quail (ppm): 26.2, 8.1, 81.6 orally. LC50 (96 hr) in bluegill, trout (ppb): 14.9, 42.4 (Maitlen).
Raw materials And Preparation ProductsBack Directory
[Raw materials]

PETROLEUM ETHER-->Sulfuryl chloride-->Cyclohexanone-->Isobutyraldehyde-->Disulfur dichloride-->Sulfur dichloride-->Carbofuran-->Dibutylamine-->DIBUTYL AMIDOSULFENYL CHLORIDE-->BIS(DIBUTYLAMINO)DISULFIDE
[Preparation Products]

CARBOFURAN-3-HYDROXY
Hazard InformationBack Directory
[General Description]

Viscous brown liquid.
[Reactivity Profile]

CARBOSULFAN(55285-14-8) is a thiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.
[Air & Water Reactions]

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.
[Potential Exposure]

Carbosulfan is a carbamate insecticide and a low toxic derivative from cabofuran. It is a broad spectrum insecticide, nematicide, miticide, effective against pests and mites. It is used to protect alfalfa, apple, citrus, corn, deciduous fruit, potato, rice, sorghum, soybean, sugar beets, sugarcane, and other vegetable, field, tree and orchard crops. It is used for seed treatments
[First aid]

Speed in removing material from eyes and skin is of extreme importance. Eyes: Eye contact can cause dangerous amounts of these chemicals to be quickly absorbed through the mucous membrane into the bloodstream. Immediately and gently flush eyes with plenty of warm or cold water (NO hot water) for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Dermal contact can cause dangerous amounts of these chemicals to be absorbed into the bloodstream. Wearing the appropriate PPE equipment and respirator for carbamate pesticides, immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Shampoo hair promptly if contaminated; protect eyes. Ingestion: Call poison control. Loosen all clothing. Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting.  If conscious, alert, and able to swallow, rinse mouth and have victim drink 4 to 8 oz of water. Check to see if poison control instructs you to use ipecac syrup, otherwise administer slurry of activated charcoal (2 oz in 8 oz of water). If victim is UNCONSCIO United States OR HAVING CONVULSIONS, do nothing except keep victim warm. In some cases you may be specifically instructed by poison control to induce vomiting by way of 2 tablespoons of syrup of ipecac (adult) washed down with a cup of water. Do NOT give activated charcoal before or with ipecac syrup. Inhalation: Get medical aid. Do not contaminate yourself. Wearing the appropriate PPE equipment and respirator for carbamate pesticides, immediately remove the victim from the contaminated area to fresh air. If the victim is not breathing, administer artificial respiration. Do not use mouth-tomouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If breathing is difficult, administer oxygen through bag/mask apparatus until medical help arrives. Do not leave victim unattended.
[Shipping]

UN2992 Carbamate pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials; UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Incompatibilities]

Carbamates are incompatible with strong oxidizing acids, peroxides, and hydro-peroxides; strong reducing agents such as hydrides; strong acids and bases. Contact with nitrides or chemically active metals (aluminum, copper, magnesium, neptunium, sodium, tin, titanium,zinc, etc.) causes the release of potentially explosive hydrogen gas and a metal salt.
[Description]

Carbosulfan (8),2,3-dihydro-2,2-dimethylbenzofuran- 7-yl(dibutylaminothio)methylcarbamate(IUPAC), is an orange to brown, clear viscous liquid (bp 124–128 ?C), miscible with organic solvents and solubility 0.3 ppm in water(25 ?C). It is closely related structurally to carbofuran,and like carbofuran, it is a cholinesterase inhibitor with systemic activity.
[Waste Disposal]

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Noncombustible containers should be crushed and buried under more than 40 cm of soil. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
[Uses]

Carbosulfan is an insecticide with contact and stomach action. It is used to control a wide range of soil-dwelling and foliar pests in cotton, sugar beet, potato, rice, fruit, maize, vegetables, sugar cane and coffee.
[Definition]

ChEBI: Carbosulfan is a member of 1-benzofurans and a carbamate ester. It has a role as an EC 3.1.1.7 (acetylcholinesterase) inhibitor, a carbamate insecticide, an acaricide, an agrochemical and a nematicide.
[Metabolic pathway]

Carbosulfan is an N-sulfenyl-N-methylcarbamate which is effectively a pro-insecticide of carbofuran. The latter is formed in vivo by the biochemical or chemical thiolysis of carbosulfan. N-S Bond cleavage, oxidation, conjugation and hydrolysis are the main metabolic routes for carbosulfan in plants and animals. Carbosulfan is degraded via carbofuran in soil. In plants, carbosulfan is metabolised via carbofuran to 3-hydroxycarbofuran (PM).
[Metabolism]

Itsmetabolic patterns are similar to those of carbofuran. In rats, it rapidly undergoes hydrolytic and oxidative processes followed by conjugation. It is not persistent in soils, with DT50 ca. 2–5 days, and it was rapidly degraded to carbofuran in a sandy loam soil (4). Carbofuran was subsequently hydrolyzed at the carbamate ester group to form the phenol carbofuran or oxidized at the 3- position. Biscarbofuran disulfide and minor products were also detected. Carbofuran was also formed in soils by nonbiological degradation processes.
[storage]

Store at -20°C
[Degradation]

Carbosulfan is hydrolysed in aqueous media most rapidly under acidic conditions. Its DT50 values (25 °C) at pH 4,6 and 7 were <1 hour, 22 hours and 7.6 days respectively (PM). In a variety of aqueous solvents there was facile cleavage of the N-S carbamate bond of carbosulfan to yield carbofuran (2) as the sole or major product (see Scheme 1) (Umetsu et al., 1980). A solution of [14C]carbosulfanin propylene glycol was treated with 0.001 or 0.01 N aqueous HCl at 40 °C. Solutions were analysed at intervals up to 24 hours. Carbosulfan was relatively stable with more than 40% being recovered after 24 hours in the solution of lower acidity. Carbofuran (2) was the principal transformation product in hydrochloric acid. Biscarbofuran disulfide (3) was present in only trace amounts and small amounts of polysulfides of carbosulfan (4,n = 2-6) were detected (Umetsu and Fukuto, 1982).
Carbosulfan was quite stable in neutral and alkaline media. [14C-carbonyl]- or [14C-dibutylamino]Carbosulfan dissolved in dichloromethane: acetic acid (9:l) converted to a range of products via N-S bond cleavage. The principal products were carbofuran (2), dibutylamine and a mixture of polysulfide derivatives: bis-carbofuran disulfide (3) and a mixture of bis-carbofuran polysulfides (5). Structures of products were confirmed by MS and NMR (Umetsu et al., 1981a,b).
Questions And AnswerBack Directory
[Chemical properties]

Brown sticky liquid. B.p. is124 ~ 128 ℃ (114 ℃). The flash point is 115~1,117℃, and the vapor pressure is 0.041 x 10-3Pa. The relative density is 1.056 (20℃). It can dissolve with acetone, ethanol and xylene, and the solubility in water is 0.3mg/L. The distribution coefficient is 157 (pH value is 7.05).
It has a fast decomposition in water, easily decomposed into carbofuran with pH<7. In the sun, when the 5 g/mL of Carbosulfan is in buffer solution with pH equaling to 7, the half-life period is 1.4d and 4 ~ 8d in distilled water.
[Application]

  • This product is a derivative of carbofuran, which has the same insecticidal activity as carbofuran .But its toxicity is much lower than carbofuran, a stomach insecticide .It can be metabolized into carbofuran in the organism and then play its effect to kill the insect. It has excellent control effect on the potato green peach aphid, black beetle, high dyed blind fly, cutworm and other insects. In addition, it can also better control cotton spider mite, billbug, tribolium confusum and spodoptera moth etc..
  • Carbamate insecticides, acaridants and nematides with high absorbability and broad-spectrum properties. It is a low toxic variety of Carbosulfan for the control of citrus, fruit trees, cotton and rice crops of aphids, mites, wireworm, beet and potato beetles, a hidden food tea leafhopper, Grapholitha molesta, codling moth and other pests. The administration concentration is 5mg/L and the effective component is 6.8 ~ 15g /100m2.
  • Low toxic insecticides with internal absorbability and broad-spectrum
  • For the control of rust ticks, aphids, thrips, leafhoppers and other more than 10 kinds of pests on the fruit trees, cotton, vegetables, grain and other crops.
[Preparation Method]

Preparation method 1:
Preparation of two n-butanamine sulphide Add two n-butyl amine and petroleum ether (60~90℃ ), mixing and cooling to 0℃ . Then slowly drip disulfur dichloride and maintain the temperature at 0~10 ℃. Afterwards, the reaction will be maintained at a constant temperature. The proportioning of the di-n-butylamine, disulfur dichloride and sulfuric chloride is 1:0.6:0.55(mol). The yield is 88%.
The synthesis of carbosulfan Two n-butanamine sulphur chloride reacts with carbosulfan with the ratio of 1:1. The reaction process is added with a proper amount of alkaline solution, and the reaction temperature is 10~20 ℃. The reaction time period is 2h. Add water and mix it for 10 minutes after the reaction. Filter it and the unreacted is carbosulfan which can be reused. The filtrate is stratified and the oil layer is decompressed and dissolving, and the yield is 90%.

Preparation method 2:
The synthesis of the intermediates hydroxyl compounds can be take the carbosulfan as reference. There are also literature reporting that starting from cyclohexanone and isobutyrate, five steps will be able to get it synthesized through condensation, chlorination, aromatization, hydrolysis and closed loop reaction. It is characterized by the synthesis of non aromatic compounds and is a highly selective synthesis route.
[Category]

Pesticides
[Toxicity classification]

Highly toxic
[Acute toxicity]

Oral administration-rats  LD50: 51 mg / kg;
Oral administration - mouse LD50: 74 mg / kg
[Flammability]

Combustible
[Hazard Characteristics]

Combustion can produce toxic nitrogen oxides and oxygen sulfide.
[Storage and transportation]

The storeroom is ventilated and dry at low temperature.
Separate transportation from food raw materials.
[Extinguisher]

Dry powder, foam, sand.
Spectrum DetailBack Directory
[Spectrum Detail]

Carbosulfan(55285-14-8)MS
Carbosulfan(55285-14-8)IR1
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