| Identification | More | [Name]
DIMETHYL 2,6-PYRIDINEDICARBOXYLATE | [CAS]
5453-67-8 | [Synonyms]
2,6-PYRIDINEDICARBOXYLIC ACID DIMETHYL ESTER
AKOS 90661
DIMETHYL 2,6-PYRIDINEDICARBOXYLATE
DIMETHYL DIPICOLINATE
DIMETHYL PYRIDINE-2,6-DICARBOXYLATE
DIPICOLINIC ACID DIMETHYL ESTER
RARECHEM AL BF 0203
dimethyl pyridine-2,6-carboxylate
Pyridine-2,6-dicarboxylic acid dimethyl ester | [EINECS(EC#)]
226-697-3 | [Molecular Formula]
C9H9NO4 | [MDL Number]
MFCD00134493 | [Molecular Weight]
195.17 | [MOL File]
5453-67-8.mol |
| Chemical Properties | Back Directory | [Melting point ]
121-125 °C(lit.)
| [Boiling point ]
100 °C(Press: 0.005 Torr) | [density ]
1.231±0.06 g/cm3(Predicted) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform | [form ]
Solid | [pka]
-0.46±0.10(Predicted) | [color ]
Off-White | [Water Solubility ]
Soluble in water(14 g/L) (25°C). Soluble in chloroform. | [InChI]
InChI=1S/C9H9NO4/c1-13-8(11)6-4-3-5-7(10-6)9(12)14-2/h3-5H,1-2H3 | [InChIKey]
SNQQJEJPJMXYTR-UHFFFAOYSA-N | [SMILES]
C1(C(OC)=O)=NC(C(OC)=O)=CC=C1 | [CAS DataBase Reference]
5453-67-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection . | [WGK Germany ]
3
| [HS Code ]
29333990 |
| Hazard Information | Back Directory | [Chemical Properties]
Off-White Solid | [Uses]
Dimethyl 2,6-pyridinedicarboxylate may be used in the synthesis of:
- ditopic macrocycle having two xylyl rings linked by diethylene glycol and 2,6-pyridinediamide spacers, which acts as host molecule capable of forming complexes with diphenylurea derivatives
- N,N′-bis(2-aminoethyl)dipicoloinic acid diamide Schiff base
- 1,1′-(2,6-bispyridyl)bis-3-(9-ethylcarbazole-3-yl)-1,3-propanedione
| [Application]
Dimethyl 2,6-pyridinedicarboxylate could be used as a starting material to synthesize four pyridine-bridged bis pyrazole ligands by Claisen condensation[1]. These ligands could be further treated with UCl4 to yield the corresponding novel mononuclear uranium(IV) complexes [UIV(R′′′2L)(Cl)4].
| [General Description]
The standard molar enthalpy of formation for dimethyl 2,6-pyridinedicarboxylate (dimethylpyridine-2,6-dicarboxylate) has been calculated from the standard molar enthalpy of combustion, which was measured by a static bomb calorimeter. | [storage]
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
| [References]
[1] Korzekwa, Jana , et al. "Synthesis and characterization of uranium(IV) tetrachloro complexes in bis-pyrazolylpyridine ligand environments." Dalton Transactions (2017):10.1039.C7DT02947K. |
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