| Identification | More | [Name]
ALLYL PHENYL SULFIDE | [CAS]
5296-64-0 | [Synonyms]
ALLYL PHENYL SULFIDE
ALLYL PHENYL SULPHIDE
(Allylsulfanyl)benzene
(Allylthio)benzene
3-(Phenylthio)prop-1-ene
3-(Phenylthio)propene
Allyl phenyl thioether
Benzene, (2-propenylthio)-
Phenyl allyl sulfide
Phenyl allyl thioether
Sulfide, allyl phenyl
Allylphenylsulfide,97%
(2-Propenylthio)benzene
2-Propenyl phenyl sulfide | [EINECS(EC#)]
226-142-5 | [Molecular Formula]
C9H10S | [MDL Number]
MFCD00014957 | [Molecular Weight]
150.24 | [MOL File]
5296-64-0.mol |
| Chemical Properties | Back Directory | [Melting point ]
-48--46.5 °C | [Boiling point ]
223-225 °C(lit.) | [density ]
1.024 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.572
| [Fp ]
>98°C | [solubility ]
insol water; sol most organic solvents | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Sensitive ]
Air Sensitive | [BRN ]
1856940 | [LogP]
3.510 | [CAS DataBase Reference]
5296-64-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R20/21:Harmful by inhalation and in contact with skin . | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 2810 6.1/PG 2
| [WGK Germany ]
3
| [RTECS ]
WR2400000 | [F ]
13 | [HS Code ]
2930.90.2900 | [HazardClass ]
6.1(b) | [PackingGroup ]
III |
| Hazard Information | Back Directory | [Synthesis Reference(s)]
Synthesis, p. 625, 1984
Tetrahedron, 47, p. 8621, 1991 DOI: 10.1016/S0040-4020(01)82405-4
Tetrahedron Letters, 20, p. 1481, 1979 | [Solubility in organics]
ALLYL PHENYL SULFIDE is insol in water; sol most in organic solvents. | [Purification Methods]
Dissolve the sulfide in Et2O, wash with alkali, H2O, dry over CaCl2, evaporate and fractionally distil it, preferably under vacuum. It should not give a precipitate with an alcoholic solution of Pb(OAc)2. [Hurd & Greengard J Am Chem Soc 52 3356 1930, Tarbell & McCall J Am Chem Soc 74 48 1952, Beilstein 6 IV 1479.] | [Preparation and handling]
ALLYL PHENYL SULFIDE can be made from Allyl Bromide and sodium thiophenolate in ethanol.
Handling, Storage, and Precautions: must be handled in a fume hood due to stench caused by contamination with Thiophenol. The pure sulfide has a more agreeable odor with a sweet overtone. No special precautions are necessary when handling in the atmosphere for weighing and transferring. In order to avoid autoxidation the sulfide should be stored in a well sealed vessel with exclusion of oxygen and moisture at 4 °C. |
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