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ChemicalBook--->CAS DataBase List--->51725-82-7

51725-82-7

51725-82-7 Structure

51725-82-7 Structure
IdentificationMore
[Name]

3-OXO-3-O-TOLYL-PROPIONIC ACID ETHYL ESTER
[CAS]

51725-82-7
[Synonyms]

Ethyl o-toluoylacetate
3-OXO-3-O-TOLYLPROPANOATE
Ethyl o-methylbenzoylacetate
ETHYL (2-METHYLBENZOYL)ACETATE
ETHYL 3-OXO-3-O-TOLYLPROPANOATE
Ethyl 2-(2-methylbenzoyl)acetate
Ethyl 3-Oxo-3-(o-tolyl)propionate
Ethyl (2-methylbenzoyl)acetate 97%
2-Methylbenzoylacetic acid ethyl ester
2-[(2-methylphenyl)-oxomethyl]butanoate
3-OXO-3-O-TOLYL-PROPIONIC ACID ETHYL ESTER
3-OXO-3-(2-TOLYL)PROPIONIC ACID ETHYL ESTER
β-Oxo-2-methylbenzenepropionic acid ethyl ester
Benzenepropanoicacid,2-methyl-β-oxo-,ethylester
3-(2-Methylphenyl)-3-oxopropionic acid ethyl ester
3-Oxo-3-(2-methylphenyl)propanoic acid ethyl ester
3-Oxo-3-(2-methylphenyl)propionic acid ethyl ester
Benzenepropanoic acid, 2-methyl-β-oxo-, ethyl ester
[Molecular Formula]

C12H14O3
[MDL Number]

MFCD03424817
[Molecular Weight]

206.24
[MOL File]

51725-82-7.mol
Chemical PropertiesBack Directory
[Boiling point ]

256-257 °C(lit.)
[density ]

1.069 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.5255(lit.)
[Fp ]

>230 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

clear liquid
[pka]

10.00±0.46(Predicted)
[color ]

Colorless to Light yellow to Light orange
[λmax]

287nm(MeOH)(lit.)
[CAS DataBase Reference]

51725-82-7(CAS DataBase Reference)
Safety DataBack Directory
[WGK Germany ]

3
[HS Code ]

2918.30.3000
Hazard InformationBack Directory
[Uses]

Reactant for:
  • Preparation of highly substituted furans by tandem condensation-cyclization reactions using bismuth triflate catalyst
  • Co/Mn-mediated oxidative cross-coupling
  • Enantioselective ruthenium-catalyzed hydrogenation
  • Preparation of cambinol analogs for sirtuin inhibition with antitumor action
[Uses]

Reactant for:• ;Preparation of highly substituted furans by tandem condensation-cyclization reactions using bismuth triflate catalyst1• ;Co/Mn-mediated oxidative cross-coupling2• ;Enantioselective ruthenium-catalyzed hydrogenation3• ;Preparation of cambinol analogs for sirtuin inhibition with antitumor action4
[General Description]

Ethyl (2-methylbenzoyl)acetate is a β-keto ester. It undergoes Co/Mn mediated oxidative coupling reaction with various indole derivatives.
Spectrum DetailBack Directory
[Spectrum Detail]

3-OXO-3-O-TOLYL-PROPIONIC ACID ETHYL ESTER(51725-82-7)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

51725-82-7(sigmaaldrich)
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