| Identification | More | [Name]
Azetidine | [CAS]
503-29-7 | [Synonyms]
AZETIDINE
TRIMETHYLENE IMINE
1,3-Propylenimine
Azacyclobutane
Azete, tetrahydro-
Trimethylenimine
Azetidine (Trimethyleneimine)
AZETIDINE 99%
tetrahydroazete | [EINECS(EC#)]
207-963-8 | [Molecular Formula]
C3H7N | [MDL Number]
MFCD00005165 | [Molecular Weight]
57.09 | [MOL File]
503-29-7.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless liquid | [Melting point ]
-70°C | [Boiling point ]
61-62 °C(lit.)
| [density ]
0.847 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.432(lit.)
| [Fp ]
−5 °F
| [storage temp. ]
2-8°C
| [form ]
Liquid | [pka]
11.29(at 25℃) | [color ]
Clear colorless | [Water Solubility ]
miscible | [Sensitive ]
Moisture Sensitive/Air Sensitive | [Detection Methods]
GC,NMR,MS | [BRN ]
102384 | [InChIKey]
HONIICLYMWZJFZ-UHFFFAOYSA-N | [CAS DataBase Reference]
503-29-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Azetidine(503-29-7) | [Storage Precautions]
Air sensitive;Store under nitrogen;Moisture sensitive | [EPA Substance Registry System]
503-29-7(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable.
R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2733 3/PG 2
| [WGK Germany ]
3
| [F ]
2-10 | [TSCA ]
Y | [HazardClass ]
3.1 | [PackingGroup ]
I | [HS Code ]
29339990 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless liquid | [Uses]
suzuki reaction | [Definition]
ChEBI: Azetidine is a saturated organic heteromonocyclic parent, a member of azetidines and an azacycloalkane. | [General Description]
Phototransformations of azetidine radical cations in freonic matrices under the action of light with λ = 436nm has been investigated. The IR spectrum of azetidine in solid argon matrices has been measured. | [Purification Methods]
Azetidine is a flammable, hygroscopic liquid smelling of ammonia, which absorbs CO2 from air and should be kept under Argon. Purify it by drying it over solid KOH and distilling it through a short Vigreux column (p 11) at atmospheric pressure (under Argon) and keeping the pot temperature below 210o. It is moisture sensitive. The hydrochloride M 93.6 has m > 300o and the hydroiodide has m 146.5o(from EtOH). The N-Me derivative has m 112o(from *C6H6/pet ether), and the Nphenylcarbamoyl derivative has m 189-190o(from EtOH). [Searles et al. J Am Chem Soc 7 8 4917 1956, Beilstein 20 H 2, 20 I 3, 20 II 3, 20 III/IV 53, 20/1 V 136.] |
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