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ChemicalBook--->CAS DataBase List--->49608-01-7

49608-01-7

49608-01-7 Structure

49608-01-7 Structure
IdentificationMore
[Name]

Ethyl 6-chloronicotinate
[CAS]

49608-01-7
[Synonyms]

6-CHLORONICOTINIC ACID ETHYL ESTER
ETHYL 6-CHLORONICOTINATE
6-Chloro Nitotinic acid Ethyl ester
6-Chloronicotinic acid ethyl ester (Ethyl-6-Chloronicotinate)
Ethyl6-chloronicotinate,97%
3-Pyridinecarboxylic acid, 6-chloro-, ethyl ester
ETHYL 6-CHLORONICOTINATE[FOR TAZAROTENE]
Ethyl 6-chloropyridine-3-carboxylate
ETHYL 2-CHLOROPYRIDINE-5-CARBOXYLATE
Ethyl 2-chloropyridine-3-carboxylate, 6-Chloronicotinic acid ethyl ester
Ethyl 6-chloropyridine-3-carboxylate ,98%
6-Chloro-3-pyridinecarboxylic acid ethyl ester
[EINECS(EC#)]

610-463-6
[Molecular Formula]

C8H8ClNO2
[MDL Number]

MFCD00082739
[Molecular Weight]

185.61
[MOL File]

49608-01-7.mol
Chemical PropertiesBack Directory
[Melting point ]

26-30 °C(lit.)
[Boiling point ]

98 °C
[density ]

1.245±0.06 g/cm3(Predicted)
[refractive index ]

1.522
[Fp ]

>230 °F
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

-1.95±0.10(Predicted)
[color ]

Colourless to Off-White Oil
[Detection Methods]

HPLC
[BRN ]

4742175
[InChIKey]

ILDJJTQWIZLGPO-UHFFFAOYSA-N
[CAS DataBase Reference]

49608-01-7(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29339900
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

6-MORPHOLINONICOTINONITRILE-->Tazarotene-->6-MORPHOLINONICOTINOHYDRAZIDE-->(6-MORPHOLINO-3-PYRIDINYL)METHANOL-->[6-(1-PYRROLIDINYL)-3-PYRIDINYL]METHANOL-->Pyridine, 5-(bromomethyl)-2-chloro- (9CI)-->6-(1-Piperazinyl)-3-pyridinecarboxylic acid ethyl ester-->3-Pyridinecarboxaldehyde, 6-(2-methyl-1H-imidazol-1-yl)--->6-(3,3,3-Trifluoropropoxy)nicotinic acid
Hazard InformationBack Directory
[Chemical Properties]

White to light yellow solid or colorless to yellow liquid
[Uses]

Ethyl 6-chloropyridine-3-carboxylate (Ethyl 6-chloronicotinate) may be used in the preparation of ethyl 5-{[5-(1H-benzimidazol-2-yl)pyridin-2-yl]ethynyl}pyridine-2-carboxylate by reacting with 2-[6-(ethynyl)pyridin-3-yl]-1H-benzimidazole under microwave irradiation.
[Uses]

Ethyl 6-chloronicotinate is a nicotinic acid derivative used in the preparation of potent H3 receptor antagonists.
[General Description]

Ethyl 6-chloropyridine-3-carboxylate (Ethyl-6-chloronicotinate, E-6-ClN) undergoes direct amidation on reacting with benzylamine in the presence lanthanum trifluoromethanesulfonate La(OTf)3. The structural and physicochemical properties of E-6-ClN have been investigated based on its spectroscopic data, time-dependent density functional theory and density of state diagrams.
Spectrum DetailBack Directory
[Spectrum Detail]

Ethyl 6-chloronicotinate(49608-01-7)IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Ethyl 6-chloronicotinate, 97%(49608-01-7)
[Sigma Aldrich]

49608-01-7(sigmaaldrich)
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