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ChemicalBook--->CAS DataBase List--->4202-14-6

4202-14-6

4202-14-6 Structure

4202-14-6 Structure
IdentificationMore
[Name]

Dimethyl acetylmethylphosphonate
[CAS]

4202-14-6
[Synonyms]

(2-OXOPROPYL)PHOSPHONIC ACID DIMETHYL ESTER
ACETONYLPHOSPHONIC ACID DIMETHYL ESTER
DIMETHYL (2-OXOPROPYL)PHOSPHONATE
DIMETHYL ACETONYLPHOSPHONATE
DIMETHYL ACETYLMETHYLPHOSPHONATE
LABOTEST-BB LT00847718
PHOSPHONIC ACID, (2-OXOPROPYL)-, DIMETHYL ESTER
Acetylmethylphosphonic acid dimethyl ester~Dimethyl acetonylphosphonate~Dimethyl (2-oxopropyl)phosphonate
Dimethyl(2-oxopropyl)phosph
Dimethylacetylmethylphosphonate,[Acetylmethylphosphonicaciddimethylester
Acetylmethylphosphonicaciddimethylester
Dimethylacetylmethylphosphonate,97+%
Dimethyl(2-oxopropyl)phosphonate, 97 %
1-Dimethoxyphosphorylpropan-2-one
Dimethyl Acetyl Methyl Phosphonate Dimethyl 2-oxopropylphosphonate
[EINECS(EC#)]

224-110-5
[Molecular Formula]

C5H11O4P
[MDL Number]

MFCD00008769
[Molecular Weight]

166.11
[MOL File]

4202-14-6.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR COLOURLESS TO LIGHT BROWN LIQUID
[Boiling point ]

76-79 °C3 mm Hg(lit.)
[density ]

1.202 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.439(lit.)
[Fp ]

200 °F
[storage temp. ]

2-8°C
[solubility ]

Difficult to mix.
[form ]

Liquid
[color ]

Clear colorless to light brown
[BRN ]

1766218
[InChIKey]

UOWIYNWMROWVDG-UHFFFAOYSA-N
[CAS DataBase Reference]

4202-14-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Dimethyl (2-oxopropyl)phosphonate(4202-14-6)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[F ]

10
[Hazard Note ]

Irritant
[HS Code ]

29310095
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Acetone-->Acetonitrile-->Potassium iodide-->Trimethyl phosphite-->Chloroacetone
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Dimethyl acetylmethylphosphonate(4202-14-6).msds
Hazard InformationBack Directory
[Chemical Properties]

CLEAR COLOURLESS TO LIGHT BROWN LIQUID
[Uses]

Reagent used together with tosyl azide in a one-pot alkynylation of aldehydes.
[Uses]

Dimethyl acetylmethylphosphonate is a Reagent used together with tosyl azide in a one-pot alkynylation of aldehydes.
[Synthesis Reference(s)]

Tetrahedron Letters, 17, p. 2829, 1976 DOI: 10.1016/S0040-4039(01)85513-1
[reaction suitability]

reaction type: C-C Bond Formation
Spectrum DetailBack Directory
[Spectrum Detail]

Dimethyl acetylmethylphosphonate(4202-14-6)MS
Dimethyl acetylmethylphosphonate(4202-14-6)1HNMR
Dimethyl acetylmethylphosphonate(4202-14-6)13CNMR
Dimethyl acetylmethylphosphonate(4202-14-6)IR1
Dimethyl acetylmethylphosphonate(4202-14-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Dimethyl (2-oxopropyl)phosphonate, 95%(4202-14-6)
[Alfa Aesar]

Dimethyl acetylmethylphosphonate, 97%(4202-14-6)
[Sigma Aldrich]

4202-14-6(sigmaaldrich)
[TCI AMERICA]

Dimethyl (2-Oxopropyl)phosphonate,>95.0%(GC)(4202-14-6)
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