| Identification | More | [Name]
(3-BROMOPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE | [CAS]
3607-17-8 | [Synonyms]
(3-BROMOPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE
BROMOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE
BTB
bromo(3-bromopropyl)triphenylphosphorane
bromo(3-bromopropyl)triphenylphosphorus
3-(bromopropyl)triphenylphosphonium
(3-Bromopropyl)triphenylphosphonium bromide, 98 % | [EINECS(EC#)]
222-770-9 | [Molecular Formula]
C21H21Br2P | [MDL Number]
MFCD00011866 | [Molecular Weight]
464.17 | [MOL File]
3607-17-8.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO OFF-WHITE CRYSTALLINE POWDER | [Melting point ]
228-230 °C(lit.) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform, Methanol | [form ]
solid | [color ]
White | [Sensitive ]
Hygroscopic | [BRN ]
6422974 | [InChIKey]
ZAHUZZUGJRPGKW-UHFFFAOYSA-M | [CAS DataBase Reference]
3607-17-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE TO OFF-WHITE CRYSTALLINE POWDER | [Uses]
(3-Bromopropyl)triphenylphosphonium Bromide is used in rearrangement reactions of cyclic organic molecules and in organic synthesis. | [Uses]
Reactant involved in:
- Synthesis of functionalized polyurethanes using cationic ring-opening polymerization and click chemistry
- Semipinacol rearrangement and direct arylation
- Olefination of benzaldehydes
- C-H activation / cycloisomerization
- Intramolecular dehydrobromination
- Cycloisomerizations of bromodienes and enynes
| [reaction suitability]
reaction type: C-C Bond Formation |
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