| Identification | More | [Name]
BIS(PHENYLTHIO)METHANE | [CAS]
3561-67-9 | [Synonyms]
1,1'-(METHYLENEBIS(THIO))BISBENZENE
1-([(PHENYLTHIO)METHYL]THIO)BENZENE
BIS(PHENYLTHIO)METHANE
DIPHENYLTHIOMETHANE
FORMALDEHYDE DIPHENYL MERCAPTAL
([(Phenylsulfanyl)methyl]sulfanyl)benzene
Benzene, 1,1'-[methylenebis(thio)]bis-
Bis(phenyithio)methane
Bis(thiophenoxy)methane
[methylenebis(thio)]bisbenzene
Formaldehydediphenylmercapatal
Bis(phenylthio)methane,98+%
Diphenylthiomethane, Formaldehyde diphenyl mercaptal
Methylenebis(phenyl sulfide)
Phenyl(phenylthiomethyl) sulfide | [EINECS(EC#)]
222-624-4 | [Molecular Formula]
C13H12S2 | [MDL Number]
MFCD00003067 | [Molecular Weight]
232.36 | [MOL File]
3561-67-9.mol |
| Chemical Properties | Back Directory | [Appearance]
light yellow crystalline powder | [Melting point ]
34-37 °C(lit.) | [Boiling point ]
194 °C8 mm Hg(lit.) | [density ]
1.2633 (rough estimate) | [refractive index ]
1.6210 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [Water Solubility ]
Insoluble in water. | [BRN ]
1874146 | [CAS DataBase Reference]
3561-67-9(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 3335 | [WGK Germany ]
3
| [F ]
13 | [HazardClass ]
STENCH | [HS Code ]
29309090 |
| Hazard Information | Back Directory | [Chemical Properties]
light yellow crystalline powder | [Uses]
Bis(phenylthio)methane (PhSCH2SPh) may be used in the synthesis of the following:
- dihydroxy thioethers
- [Cu4I4{μ-PhS2CH2SPh}2]n
- [(η5-C5Me5)MCl2(η1-(PhS)2CH2)] (M=Rh, Ir ; C5Me5= pentamethylcyclopentadienyl)
- 6-deoxy-1,2:3,4-di-O-isopropylidene-α-D-galactoheptodialdo-1,5-pyranose diphenyl dithioacetal
| [Synthesis Reference(s)]
Synthetic Communications, 19, p. 31, 1989 DOI: 10.1080/00397918908050949
Synthesis, p. 447, 1975 DOI: 10.1055/s-1975-23797 | [General Description]
Bis(phenylthio)methane (PhSCH2SPh) is a dithioether ligand. It forms coordination complex with silver(I) salts. It participates in the synthesis of (-)-rasfonin. |
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