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ChemicalBook--->CAS DataBase List--->3486-35-9

3486-35-9

3486-35-9 Structure

3486-35-9 Structure
IdentificationMore
[Name]

Zinc carbonate
[CAS]

3486-35-9
[Synonyms]

ZINC CARBONATE
ZINC CARBONATE, BASIC, MONOHYDRATE
c.i.77950
Carbonicacid,zincsalt(1:1)
carbonuredezinc
ci77950
naturalsmithsonite
zinccarbonate(1:1)
zincmonocarbonate
zincspar
ZINC CARBONATE, 99.999%
smithsonite
Zinccarbonatehydroxidehydrate,ReagentGrade
ZINC CARBONATE, 99.99%
ZINCCARBONATEBASIC,POWDER,REAGENT
Zinkcarbonat
Zinc Carbonate, Powder
[EINECS(EC#)]

222-477-6
[Molecular Formula]

CO3Zn
[MDL Number]

MFCD00151660
[Molecular Weight]

125.4
[MOL File]

3486-35-9.mol
Chemical PropertiesBack Directory
[Appearance]

White, crystalline powder. Evolves carbon dioxide at 300C. Soluble in acids, alkalies, and ammonium salt solutions; insoluble in water.
[Melting point ]

decomposes [KIR84]
[density ]

4,398 g/cm3
[solubility ]

soluble in dilute acid solutions, alkaline solutions
[form ]

Solid
[color ]

White
[Stability:]

Stable. Incompatible with acids.
[Water Solubility ]

mol/L solution H2O: 1.64×10?4 (solubility is given at Pco2=0.00032 bar) [KRU93]; soluble dilute acids, alkalies, NH3 solutions [MER06]
[Solubility Product Constant (Ksp)]

pKsp: 9.94
[Dielectric constant]

9.3(Ambient)
[InChI]

InChI=1S/2CH2O3.4H2O.3O.5Zn/c2*2-1(3)4;;;;;;;;;;;;/h2*(H2,2,3,4);4*1H2;;;;;;;;/q;;;;;;;;;;;;2*+2/p-4
[InChIKey]

LILHXQCLSOZSRO-UHFFFAOYSA-J
[SMILES]

C([O-])([O-])=O.C([O-])([O-])=O.O=[Zn].O=[Zn].O=[Zn].O.O.O.O.[Zn+2].[Zn+2]
[CAS DataBase Reference]

3486-35-9(CAS DataBase Reference)
[EPA Substance Registry System]

3486-35-9(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

White, crystalline powder. Evolves carbon dioxide at 300C. Soluble in acids, alkalies, and ammonium salt solutions; insoluble in water.
[Uses]

Antiseptic (topical); astringent.
[General Description]

A white crystalline solid or powder that is insoluble in water. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. Used in pharmaceuticals, to make other zinc compounds, as a feed additive.
[Reactivity Profile]

ZINC CARBONATE(3486-35-9) reacts with acids to generate carbon dioxide and a zinc-containing solution. Dissolves in bases and in solutions of ammonium salts.
[Air & Water Reactions]

Insoluble in water.
[Health Hazard]

INHALATION OF DUST OR FUMES: Dry throat, cough and chest discomfort. Fever and sweating. SKIN: Astringent. INGESTION: May cause nausea and vomiting.
[Fire Hazard]

Behavior in Fire: Could decompose to liberate CO 2
[Definition]

ChEBI: Zinc carbonate is an organooxygen compound.
[Flammability and Explosibility]

Notclassified
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sulfuric acid-->Sodium carbonate-->Potassium permanganate-->Zinc oxide-->Zinc sulphate-->Zinc carbonate hydroxide
[Preparation Products]

Zinc oxide-->zinc oxide desulphurizer-->ZINC TETRAFLUOROBORATE HYDRATE-->Zinc trifluoromethanesulfonate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Zinc carbonate(3486-35-9).msds
Safety DataBack Directory
[Safety Profile]

An experimental teratogen. When heated to decomposition it emits toxic fumes of CO and Zn.
[Hazardous Substances Data]

3486-35-9(Hazardous Substances Data)
Questions And AnswerBack Directory
[Physical Properties]

White crystalline solid; orthorhombic structure; refractive index 1.818; Mohs hardness 4.3; decomposes at 300°C forming zinc oxide; practically insoluble in water, 10 mg/L at 15°C; soluble in acids, alkalis, and ammonium salt solutions.
[Occurrence and Uses]

Zinc carbonate occurs in nature as mineral smithsonite and zincspar. The compound is used in ceramics and fire proofing filler for rubber and plastics.Also, it is used in lotions, ointments, cosmetics, and as a topical antiseptic.
[Production]

Zinc carbonate is derived from its mineral smithsonite. Also, the compound may be prepared by the reaction of sodium bicarbonate with a soluble zinc salt:
ZnCl2 + NaHCO3 → ZnCO3 + NaCl + HCl
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