| Identification | More | [Name]
N-(tert-Butyl)benzylamine | [CAS]
3378-72-1 | [Synonyms]
AKOS BC-1243
N-BENZYL-T-BUTYLAMINE
N-BENZYL-TERT-BUTYLAMINE
N-TERT-BUTYLBENZYLAMINE
TERT-BUTYL-BENZYLAMINE
benzyl-tert-butyl-amine
n-(1,1-dimethylethyl)-benzenemethanamin
N-(1,1-dimethylethyl)-Benzenemethanamine
N-(1,1-Dimethylethyl)benzylamine
N-Benzyl-2-methyl-2-propanamine
N-Benzylisobutylamine
N-t-Butylbenzylamine
N-Benzyl-N-tert-butylamine
N-TERT-BUTYLBENZYLAMUINE
Benzenemethanamine, N-(1,1-dimethylethyl)-
(N-TERT-BUTYL)BENZYLAMINESALBUTAMOL
N-Benzyl-tert-butylamine, 97+%
2-Methyl-N-(phenylmethyl)propan-2-amine
N-tert-Butylbenzylamine ,99%
N-Benzyl-2-methylpropane-2-amine | [EINECS(EC#)]
222-179-6 | [Molecular Formula]
C11H17N | [MDL Number]
MFCD00008798 | [Molecular Weight]
163.26 | [MOL File]
3378-72-1.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR COLOURLESS TO PALE YELLOW LIQUID | [Melting point ]
-25 °C
| [Boiling point ]
80 °C5 mm Hg(lit.)
| [density ]
0.881 g/mL at 25 °C(lit.)
| [vapor pressure ]
12.1Pa at 25℃ | [refractive index ]
n20/D 1.497(lit.)
| [Fp ]
176 °F
| [storage temp. ]
Store below +30°C. | [solubility ]
2g/l | [form ]
Oil | [pka]
9.77±0.29(Predicted) | [color ]
Colourless | [Water Solubility ]
2 g/L (20 ºC) | [Sensitive ]
Air Sensitive | [Detection Methods]
GC,NMR | [BRN ]
507464 | [Dielectric constant]
3.2400000000000002 | [InChIKey]
DLSOILHAKCBARI-UHFFFAOYSA-N | [LogP]
2.9 at 25℃ | [CAS DataBase Reference]
3378-72-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzenemethanamine, N-(1,1-dimethylethyl)-(3378-72-1) | [Storage Precautions]
Store under nitrogen;Air sensitive | [EPA Substance Registry System]
3378-72-1(EPA Substance) |
| Questions And Answer | Back Directory | [Preparation]
N-(tert-Butyl)benzylamine can be prepared by refluxing condensation of tert-butylamine and benzyl chloride in dimethylformamide. |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi | [Risk Statements ]
R34:Causes burns.
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
2735 | [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29214980 |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS TO PALE YELLOW LIQUID | [Uses]
N-Benzyl-tert-butylamine, is used as a protected amine. It aids in the oxidation to the corresponding hydroxylamine and nitrone. | [Synthesis Reference(s)]
Tetrahedron Letters, 36, p. 9555, 1995 DOI: 10.1016/0040-4039(95)02046-2 | [Purification Methods]
Dissolve the amine in Et2O, dry it over KOH pellets, filter and fractionate it in a N2 atmosphere to avoid reaction with CO2 from the air. The hydrochloride has m 245-246o(dec) (from MeOH/Me2CO) and the perchlorate has m 200-201o. [Freidfelder et al. J Am Chem Soc 80 4320 1958, Beilstein 12 IV 2166.] |
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