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ChemicalBook--->CAS DataBase List--->27973-29-1

27973-29-1

27973-29-1 Structure

27973-29-1 Structure
IdentificationBack Directory
[Name]

1,6-Dibromopyrene
[CAS]

27973-29-1
[Synonyms]

6-DibroMopyrene
1,6-Dibromopyrene
1,6-dlbrornopyrone
Pyrene, 1,6-dibromo-
[EINECS(EC#)]

1308068-626-2
[Molecular Formula]

C16H8Br2
[MDL Number]

MFCD09263746
[MOL File]

27973-29-1.mol
[Molecular Weight]

360.04
Chemical PropertiesBack Directory
[Melting point ]

228.0 to 232.0 °C
[Boiling point ]

469.6±18.0 °C(Predicted)
[density ]

1.852±0.06 g/cm3(Predicted)
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

Chloroform (Very Slightly, Heated), Methanol (Very Slightly, Heated)
[form ]

Solid
[color ]

White to Off-White
[λmax]

246nm(EtOH)(lit.)
[InChI]

InChI=1S/C16H8Br2/c17-13-8-4-10-2-6-12-14(18)7-3-9-1-5-11(13)16(10)15(9)12/h1-8H
[InChIKey]

JRCJYPMNBNNCFE-UHFFFAOYSA-N
[SMILES]

C1(Br)=C2C3=C4C(C=C2)=CC=C(Br)C4=CC=C3C=C1
Hazard InformationBack Directory
[Chemical Properties]

white powder
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[HS Code ]

29039990
Questions and Answers (Q&A)Back Directory
[Description]

1, 6-dibromopyrene is a kind of pyrene chemical. It is majorly used as organic intermediate, OLED (organic light-emitting diodes) materials and photoelectric material. It, together with its 1, 8- isomer, can be produced by the double bromination of pyrene with bromine. It can be applied to the synthesis of bipyridine and terpyridine based ruthenium metallosynthons.
[References]

Goze, Christine, et al. "Synthesis of bipyridine and terpyridine based ruthenium metallosynthons for grafting of multiple pyrene auxiliaries."Tetrahedron letters 44.48 (2003): 8713-8716.
Kaplunov, Mikhail G., et al. "Novel 1, 8-bis(diarylamino)pyrenes as OLED materials." Mendeleev Communications 26.5(2016):437-439.
Gong, Xiaojie, et al. "Two Symmetrically Bis‐substituted Pyrene Derivatives: Synthesis, Photoluminescence, and Electroluminescence." Chinese Journal of Chemistry 33.8 (2015): 967-973.
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