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ChemicalBook--->CAS DataBase List--->2469-55-8

2469-55-8

2469-55-8 Structure

2469-55-8 Structure
IdentificationMore
[Name]

1,3-BIS(3-AMINOPROPYL)TETRAMETHYLDISILOXANE
[CAS]

2469-55-8
[Synonyms]

1,3-BIS(3-AMINOPROPYL)-1,1,3,3-TETRAMETHYLDISILOXANE
1,3-BIS(3-AMINOPROPYL)TETRAMETHYLDISILOXANE
1,3-BIS(AMINOPROPYL)TETRAMETHYLDISILOXANE
BIS(3-AMINOPROPYL)TETRAMETHYLDISILOXANE
BIS(AMINOPROPYL)TETRAMETHYLDISILOXANE
TETRAMETHYL-1,3-BIS(3-AMINOPROPYL)DISILOXANE
1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyl-disiloxan
1,3-bis(3-aminopropyl)tetramethyldislloxane
1-Propanamine,3,3’-(1,1,3,3-tetramethyl-1,3-disiloxanediyl)bis-
3,3’-(1,1,3,3-tetramethyl-1,3-disiloxanediyl)bis-1-propanamin
3,3’-(1,1,3,3-tetramethyl-1,3-disiloxanediyl)bis-1-Propanamine
9-diamine,4,4,6,6-tetramethyl-5-oxa-6-disilanonane-1
ar96447
b1710
bis(.gamma.-Aminopropyl)tetramethyldisiloxane
oxybis((3-aminopropyl)dimethyl-silan
oxybis((3-aminopropyl)dimethylsilane)
3,3'-(1,1,3,3-tetramethyldisiloxane-1,3-diyl)bispropylamine
1,3-BIS(3-AMINOPROPYL)-1,1,3,3-TETRAMETH
1,3-BIS(3-AMINOPROPYL)-1,1,3,3-TETRAMETH YLDISILOXA
[EINECS(EC#)]

219-588-7
[Molecular Formula]

C10H28N2OSi2
[MDL Number]

MFCD00039786
[Molecular Weight]

248.51
[MOL File]

2469-55-8.mol
Chemical PropertiesBack Directory
[Boiling point ]

132 °C11 mm Hg(lit.)
[density ]

0.901 g/mL at 20 °C(lit.)
[vapor pressure ]

0.27Pa at 20℃
[refractive index ]

n20/D 1.451
[Fp ]

91°C
[storage temp. ]

2-8°C
[form ]

clear liquid
[pka]

10.96±0.10(Predicted)
[color ]

Colorless to Light yellow to Light orange
[Specific Gravity]

0.897
[Water Solubility ]

Slightly soluble in water.
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[Sensitive ]

Air Sensitive
[BRN ]

1760876
[InChIKey]

GPXCORHXFPYJEH-UHFFFAOYSA-N
[LogP]

1.3 at 20℃
[CAS DataBase Reference]

2469-55-8(CAS DataBase Reference)
[EPA Substance Registry System]

1-Propanamine, 3,3'-(1,1,3,3-tetramethyl-1,3-disiloxanediyl)bis- (2469-55-8)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3267 8/PG 2
[WGK Germany ]

3
[RTECS ]

JM9235000
[F ]

10-21
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29319090
[Toxicity]

LD50 ipr-mus: 80 mg/kg RCRVAB 38,975,69
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless to pale yellow liquid
[Production Methods]

A glass flask with a stirrer, reflux condenser, thermometer, and dropping funnel was charged with N, N-bis(trimethylsilyl)allylamine. A 4% isopropyl alcohol solution of H2 PtCl6.6H2 O. From the funnel, dimethyl ethoxy silane was added dropwise to the flask at 70° C. over 3 hours for hydrosilylation reaction. The reaction solution was ripened for one hour at the temperature. After adding ethanol and dodecylbenzenesulfonic acidd, the reaction solution was refluxed for 6 hours, completing the desilylation reaction. The reaction solution was transferred to a distillation apparatus where the ethanol and trimethyl ethoxy silane were distilled under atmospheric pressure. Water was added to the remainder, which was refluxed for 2 hours. Vacuum distillation was then carried out to collect 1,3-Bis(3-aminopropyl)tetramethyldisiloxane.
[Flammability and Explosibility]

Nonflammable
[Safety Profile]

Poison by intraperitoneal route. When heated to decomposition it emits toxic vapors of NOx.
Questions and Answers (Q&A)Back Directory
[Uses]

1,3-Bis(3-aminopropyl)tetramethyldisiloxane is an endcapper for the synthesis of aminopropyl-terminated silicone fluids and for the production of silicone-epoxy and silicone polyimide copolymers especially useful in electronics applications. A unique manufacturing process insures that It has only gamma - aminopropyl substitution and none of the beta isomer. This is expected to give better reactivity in copolymer synthesis and improved heat stability.
1,3-Bis(3-aminopropyl)tetramethyldisiloxane is an alkaline material due to its amine reactive groups. Care should be exercised in handling it to prevent contact with skin and eyes. Wear safety glasses with side shields and rubber gloves when handling.
Spectrum DetailBack Directory
[Spectrum Detail]

1,3-Bis(3-aminopropyl)tetramethyldisiloxane(2469-55-8)MS
1,3-Bis(3-aminopropyl)tetramethyldisiloxane(2469-55-8)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

1,3-Bis(aminopropyl)tetramethyldisiloxane, 97%(2469-55-8)
[Sigma Aldrich]

2469-55-8(sigmaaldrich)
[TCI AMERICA]

1,3-Bis(3-aminopropyl)tetramethyldisiloxane  [Monomer for silicon modified polyamides],>80.0%(GC)(2469-55-8)
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