| Identification | More | [Name]
1,6-HEPTADIYNE | [CAS]
2396-63-6 | [Synonyms]
1,6-HEPTADIYNE
1,6-HEPTADIYNE 98%
1,6-Heptadiyne, 97+%
1,6-Heptadiyne (6CI, 8CI, 9CI)
Heptane-1,6-diyne | [EINECS(EC#)]
219-253-5 | [Molecular Formula]
C7H8 | [MDL Number]
MFCD00014925 | [Molecular Weight]
92.14 | [MOL File]
2396-63-6.mol |
| Safety Data | Back Directory | [Hazard Codes ]
F | [Risk Statements ]
R11:Highly Flammable. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges . | [RIDADR ]
UN 3295 3/PG 2
| [WGK Germany ]
2
| [RTECS ]
MI5600000
| [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29012990 |
| Hazard Information | Back Directory | [Chemical Properties]
clear yellow liquid | [Uses]
1,6-Heptadiyne may be used in the preparation of free-standing polymer films of poly(1,6-heptadiyne). | [Uses]
1,6-Heptadiyne may be used in the preparation of free-standing polymer films of poly(1,6-heptadiyne). Polymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct. | [General Description]
Polymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct. Cyclocopolymerization of 1,6-heptadiyne with dipropargyl ether under nitrogen atmosphere using KSCN, KBr and KI as initiators in N,N-dimethyl formamide has been studied. |
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