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ChemicalBook--->CAS DataBase List--->2232-08-8

2232-08-8

2232-08-8 Structure

2232-08-8 Structure
IdentificationMore
[Name]

1-[(4-Methylphenyl)sulfonyl]-1H-imidazole
[CAS]

2232-08-8
[Synonyms]

1-(P-TOLUENESULFONYL)-1H-IMIDAZOLE
1-(P-TOLUENESULFONYL)IMIDAZOLE
1-(TOLUENE-4-SULFONYL)IMIDAZOLE
1-TOSYLIMIDAZOLE
Tosylimidazole
1-(p-toluenesulphonyl)imidazole
1-(PARA-TOLUENESULPHONYL)IMIDAZOLE
1-(P-toluenesulfonyl)-imidazole, HPLC 99%
1-[(4-Methylphenyl)sulfonyl]-1H-imidazole
1H-IMIDAZOLE, 1-[(4-METHYLPHENYL)SULFONYL]-
1-(Toluene-4-sulfonyl)-1H-imidazole
1-(4-Methylphenyl)sulphonyl-1H-imidazole
1-Tosyl-1H-imidazole
1-(p-Toluenesulfonyl)imidazole ,99%
4-Methylphenyl(1H-imidazole-1-yl) sulfone
[EINECS(EC#)]

218-771-9
[Molecular Formula]

C10H10N2O2S
[MDL Number]

MFCD00005285
[Molecular Weight]

222.26
[MOL File]

2232-08-8.mol
Chemical PropertiesBack Directory
[Appearance]

white to slightly yellow crystals
[Melting point ]

76-78 °C(lit.)
[Boiling point ]

409.1±38.0 °C(Predicted)
[density ]

1.3038 (rough estimate)
[refractive index ]

1.5650 (estimate)
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

chloroform: soluble25mg/mL, clear, colorless to faintly yellow
[form ]

Crystals or Crystalline Powder
[pka]

1.22±0.10(Predicted)
[color ]

White to slightly yellow
[Sensitive ]

Moisture Sensitive
[Detection Methods]

HPLC
[BRN ]

612451
[InChIKey]

YJYMYJRAQYREBT-UHFFFAOYSA-N
[CAS DataBase Reference]

2232-08-8(CAS DataBase Reference)
[Storage Precautions]

Moisture sensitive
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[F ]

10-21
[HS Code ]

29332900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Chloroform-->Tosyl chloride-->Imidazole-->1-(3-SULFO-4-PHENOXY)-PHENYL-3-HEPTADECYL-4-ISOPROPYL-PYRAZOLINE-5-ONE-->4-Methylbenzenesulfonhydrazide-->P-TOLUENESULFINIC ACID-->P-Toluenesulfonic anhydride-->Sodium p-toluenesulfinate-->p-Toluenesulfonic acid-->1,1'-Carbonyldiimidazole
[Preparation Products]

Benzene, [(2,2,2-trifluoroethoxy)methyl]--->1H-Isoindol-1-one, 3-hydroxy--->Chlorotrimethylsilane
Hazard InformationBack Directory
[Chemical Properties]

white to slightly yellow crystals
[Uses]

1-(p-Toluenesulfonyl)imidazole was used in the synthesis of cationic water soluble cyclodextrin, mono-6A-(1-butyl-3-imidazolium)-6A-deoxy-β-cyclodextrin chloride (BIMCD), useful in chiral separation of amino acids and anionic pharmaceuticals by capillary electrophoresis.
[Uses]

Alcohols to azides in one step.1
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 45, p. 547, 1980 DOI: 10.1021/jo01291a044
[General Description]

1-(p-Toluenesulfonyl)imidazole converts alcohols to azides in one step.
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-(p-Toluenesulfonyl)imidazole, 99%(2232-08-8)
[Sigma Aldrich]

2232-08-8(sigmaaldrich)
[TCI AMERICA]

1-(p-Toluenesulfonyl)imidazole,>98.0%(LC)(N)(2232-08-8)
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