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ChemicalBook--->CAS DataBase List--->18742-02-4

18742-02-4

18742-02-4 Structure

18742-02-4 Structure
IdentificationMore
[Name]

2-(2-Bromoethyl)-1,3-dioxolane
[CAS]

18742-02-4
[Synonyms]

2-(2-BROMOETHYL)-1,3-DIOXOLANE
3-BROMOPROPIONALDEHYDE ETHYLENE ACETAL
1,3-Dioxolane, 2-(2-bromoethyl)-
4-(cyclopropylcarbonyl)-2,2-dimethylbenzeneacetonitrile
2-(2-BROMOETHYL)-1,3-DIOXOLANE, STAB.
2-(2-Bromoethyl)-1,3-dioxolane, stabilized, 96%
Bromoethyldioxolane
2-(2-Bromoethyl) 1,3-Dioxolane (Bedo)
3-bromopropanal 1,2-ethanediol acetal
1-BROMO-3,3-(ETHYLENEDIOXY)-PROPANE
2-(2-Bromoethyl)-1,3-dioxolane, 95%, stab. with silver
[2-(1,3-Dioxolane-2-yl)ethyl] bromide
2-(1,3-Dioxolane-2-yl)ethyl bromide
3-Bromopropanal ethylene acetal
[EINECS(EC#)]

242-551-1
[Molecular Formula]

C5H9BrO2
[MDL Number]

MFCD00003216
[Molecular Weight]

181.03
[MOL File]

18742-02-4.mol
Chemical PropertiesBack Directory
[Appearance]

clear yellow to brown liquid
[Boiling point ]

68-70 °C8 mm Hg(lit.)
[density ]

1.542 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.479(lit.)
[Fp ]

149 °F
[storage temp. ]

2-8°C
[color ]

brownish-yellow
[Specific Gravity]

1.541.542
[Water Solubility ]

immiscible
[Sensitive ]

Light Sensitive
[BRN ]

103516
[InChIKey]

GGZQLTVZPOGLCC-UHFFFAOYSA-N
[CAS DataBase Reference]

18742-02-4(CAS DataBase Reference)
[NIST Chemistry Reference]

2-(2-Bromoethyl)-1,3-dioxolane(18742-02-4)
[Storage Precautions]

Store under inert gas
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 2810 6.1/PG 3
[WGK Germany ]

2
[F ]

8-9
[HazardClass ]

6.1
[PackingGroup ]

[HS Code ]

29329990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Phosphoric acid-->Ethylene glycol-->Acrolein-->Sodium bromide
[Preparation Products]

Bexagliflozin-->3-(1,3-DIOXOLAN-2-YL)-1-(3-(TRIFLUOROMETHYL)PHENYL)PROPAN-1-ONE-->2-Cyclopropoxyethyl4-methylbenzenesulfonate-->(1,3-DIOXOLAN-2-YLETHYL)MAGNESIUM BROMIDE-->4-broMo-1-chloro-2-(4-(2-cyclopropoxyethoxy)benzyl)benzene
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3-Bromopropionaldehyde ethylene acetal(18742-02-4).msds
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless to yellow or brown liquid
[Uses]

Alkylating agent for amines,1 dithianes,2 and carboximides,3 and via the Grignard reagent, aldehydes.4
[General Description]

Copper-catalyzed borylation of 2-(2-bromoethyl)-1,3-dioxolane with bis(pinacolato)diboron followed by treatment with potassium bifluoride affords the key organotrifluoroborate reagent.
[Purification Methods]

Dissolve it in pentane, wash with 5% aqueous NaHCO3, dry (Na2SO4), and evaporate. Distil the residue. [NMR: Büchi & Wüest J Org Chem 34 1122 1969, Kriesat & Gisvold J Pharm Sci 60 1250 1971, Beilstein 19/1 V 69.]
Spectrum DetailBack Directory
[Spectrum Detail]

2-(2-Bromoethyl)-1,3-dioxolane(18742-02-4)MS
2-(2-Bromoethyl)-1,3-dioxolane(18742-02-4)1HNMR
2-(2-Bromoethyl)-1,3-dioxolane(18742-02-4)IR1
2-(2-Bromoethyl)-1,3-dioxolane(18742-02-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-(2-Bromoethyl)-1,3-dioxolane, 96%(18742-02-4)
[Alfa Aesar]

2-(2-Bromoethyl)-1,3-dioxolane, 95%, stab. with silver(18742-02-4)
[Sigma Aldrich]

18742-02-4(sigmaaldrich)
[TCI AMERICA]

2-(2-Bromoethyl)-1,3-dioxolane,>90.0%(GC)(18742-02-4)
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