| Identification | More | [Name]
(Trimethylsilyl)methylamine | [CAS]
18166-02-4 | [Synonyms]
2-AMINOMETHYLTRIMETHYLSILANE
(AMINOMETHYL)TRIMETHYLSILANE
(TRIMETHYLSILYL)METHYLAMINE
Methylamine, 1-(trimethylsilyl)-,
1-(trimethylsilyl)methylamine
Aminomethyltrimethylsilane**CUSTOMSYNTHESISPLEASEASK**
(trimethylsilyl)methanamine
AMTMS
Trimethylsilylmethaneamine | [EINECS(EC#)]
242-049-2 | [Molecular Formula]
C4H13NSi | [MDL Number]
MFCD00042931 | [Molecular Weight]
103.24 | [MOL File]
18166-02-4.mol |
| Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable.
R34:Causes burns.
R37:Irritating to the respiratory system. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2733 3/PG 2
| [WGK Germany ]
3
| [F ]
3-10 | [TSCA ]
No | [HazardClass ]
3.1 | [PackingGroup ]
II |
| Hazard Information | Back Directory | [Purification Methods]
A possible contaminant is hexamethyldisiloxane. It should have two 1H NMR signals in CDCl3; if not, dissolve it in *C6H6, shake it with 15% aqueous KOH, separate, dry (Na2SO4), filter, evaporate and distil it using a still of ca 10 theoretical plates. The water azeotrope has b 83o/735mm; hence it is important to dry the extract well. The hydrochloride has m 198-199o (from MeOH or Me2CO). [Noll et al. J Am Chem Soc 73 3867 1951, Beilstein 4 IV 3878.] |
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