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ChemicalBook--->CAS DataBase List--->174813-82-2

174813-82-2

174813-82-2 Structure

174813-82-2 Structure
IdentificationBack Directory
[Name]

Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
[CAS]

174813-82-2
[Synonyms]

[(R,R)-TsDPEN-Ru(Mesitylene)Cl]
Chloro[(1R,2R)-N-(p-toluenesulfonyl)-1,2-diphenylethanediamine](mesitylene)ruthenium(II)
Chloro[[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido](mesitylene)ruthenium(II)
[R-(R*,R*)]-[N-(2-Amino-1,2-diphenylethyl)-4-methylbenzenesulfonamidato-N,N']chloro[(1,2,3,4,6-η)-1,3,5-trimethylbenzene]ruthenium
Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(Mesitylene)rutheniuM(II),90% RuCl[(R,R)-Tsdpen(Mesitylene)
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(
mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
[Molecular Formula]

C30H30ClN2O3RuS-
[MDL Number]

MFCD12545951
[MOL File]

174813-82-2.mol
[Molecular Weight]

635.159
Chemical PropertiesBack Directory
[Melting point ]

241-249°C
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

orange
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[WGK Germany ]

3
[HS Code ]

2931.90.6000
Questions And AnswerBack Directory
[Reactions]

Catalyst used in the asymmetric transfer hydrogenation of ketones using formic acid-triethylamine mixture. Reactions of 174813-82-2
Hazard InformationBack Directory
[Uses]

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:
  • (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
  • Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.
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