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ChemicalBook--->CAS DataBase List--->15356-60-2

15356-60-2

15356-60-2 Structure

15356-60-2 Structure
IdentificationMore
[Name]

(+)-MENTHOL
[CAS]

15356-60-2
[Synonyms]

(1S,2R,5S)-2-ISOPROPYL-5-METHYLCYCLOHEXANOL
(1S,2R,5S)-(+)-MENTHOL
D-MENTHOL
D-P-MENTHAN-3-OL
(+)-MENTHOL
MENTHOL, (+)-
(+)-P-MENTHAN-3-OL
(1S)-(+)-menthol
5-methyl-2-(1-methylethyl)-,[1S-(1.alpha.,2.beta.,5.alpha.)]-Cyclohexanol
5-methyl-2-(1-methylethyl)-,[1s-(1alpha,2beta,5alpha)]-cyclohexano
(+)-MENTHOL, TERPENE STANDARD
(1S,2R,5S)-(+)-MENTHOL, 99% (96% EE/GLC)
(+)-Menthol=D-Menthol
Cyclohexanol, 5-methyl-2-(1-methylethyl)-, (1S,2R,5S)-
(+)-Menthol, (1S,2R,5S)-2-Isopropyl-5-methylcyclohexanol
(1S,3S,4R)-p-Menthane-3-ol
(1S,3S,4R)-p-Menthane-3α-ol
[1S,2R,5S,(+)]-2-Isopropyl-5-methylcyclohexan-1-ol
[EINECS(EC#)]

239-387-8
[Molecular Formula]

C10H20O
[MDL Number]

MFCD00062983
[Molecular Weight]

156.27
[MOL File]

15356-60-2.mol
Chemical PropertiesBack Directory
[Melting point ]

43-44 °C (lit.)
[Boiling point ]

103-104 °C/9 mmHg (lit.)
[density ]

0.890
[vapor pressure ]

0.8 mm Hg ( 20 °C)
[refractive index ]

50 ° (C=10, EtOH)
[Fp ]

196 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

15.30±0.60(Predicted)
[color ]

Colourless to Off-White Oil
[Odor]

mentholic
[optical activity]

[α]23/D +48°, c = 10 in ethanol
[Water Solubility ]

Soluble in methanol (almost transparency), chloroform, alcohols, water (456 mg/L at 25°C), and ether.
[BRN ]

1902292
[Dielectric constant]

3.2(Ambient)
[LogP]

3.15 at 25℃
[CAS DataBase Reference]

15356-60-2(CAS DataBase Reference)
[EPA Substance Registry System]

Cyclohexanol, 5-methyl-2-(1-methylethyl)-, (1S,2R,5S)- (15356-60-2)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
[RIDADR ]

UN1230 - class 3 - PG 2 - Methanol, solution
[WGK Germany ]

2
[RTECS ]

OT0700000
[TSCA ]

Yes
[HS Code ]

29061100
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Ethyl (R)-2-hydroxy-4-phenylbutyrate-->Cyclohexane, 2-(ethenyloxy)-4-methyl-1-(1-methylethyl)-, (1R,2S,4S)--->MONO-(1S)-(+)-MENTHYL PHTHALATE
Hazard InformationBack Directory
[Description]

(+)-Menthol is a monoterpene alcohol that has been found in Cannabis and has antifungal activity. It inhibits the growth of F. verticillioides (MIC = 1.5 mM). Unlike (–)-menthol, (+)-menthol does not exhibit analgesia, antibacterial, anticancer, or cholinesterase inhibitory activities.
[Chemical Properties]

(+)-MENTHOL is white low melting solid
[Uses]

(+)-MENTHOL is used for oral gel patch or film containing herb extracts or Chinese medicine, fruit extract, spearmint, and menthol for smoking cessation.
[Uses]

(1S,2R,5S)-(+)-menthol can undergo acylation with acid anhydrides in the presence of trimethylsilyl trifluoromethanesulfonate to form the corresponding acylated products.
[Definition]

ChEBI: (+)-menthol is a p-menthan-3-ol which has (1S,2R,5S)-stereochemistry. In contrast to (-)-menthol, the (+)-enantiomer occurs only rarely in nature. It is an enantiomer of a (-)-menthol.
[General Description]

(1S,2R,5S)-(+)-menthol is a chiral secondary alcohol. Its alcohol group can be protected as 2-tetrahydrofuranyl ether by reacting with bromotrichloromethane and tetrahydrofuran.
[Synthesis]

Prod.: by Meerwein-Ponndorf-Verley reduction of l-Menthone, resuhing in approximately two-thirds d-Neomenthol plus one-third i-Menthol. It can also be produced by reduction of d-Menthone.
Spectrum DetailBack Directory
[Spectrum Detail]

(+)-MENTHOL(15356-60-2)1HNMR
(+)-MENTHOL(15356-60-2)IR
(+)-MENTHOL(15356-60-2)Raman
(+)-MENTHOL(15356-60-2)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

D-Menthol, 99%(15356-60-2)
[Sigma Aldrich]

15356-60-2(sigmaaldrich)
[TCI AMERICA]

(+)-Menthol,>99.0%(GC)(15356-60-2)
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