| Identification | More | [Name]
Methyl 4-bromo-3-methylbenzoate | [CAS]
148547-19-7 | [Synonyms]
4-BROMO-3-METHYLBENZOIC ACID METHYL ESTER
4-BROMO-M-TOLUIC ACID METHYL ESTER
METHYL 4-BROMO-3-METHYLBENZOATE
METHYL 4-BROMO-M-TOLUATE
Methyl 4-Bromo-3-Methoxynicotinate | [EINECS(EC#)]
629-103-4 | [Molecular Formula]
C9H9BrO2 | [MDL Number]
MFCD00673014 | [Molecular Weight]
229.07 | [MOL File]
148547-19-7.mol |
| Chemical Properties | Back Directory | [Melting point ]
38-44 °C (lit.) | [Boiling point ]
287.4±20.0 °C(Predicted) | [density ]
1.433±0.06 g/cm3(Predicted) | [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
soluble in Methanol | [form ]
Low Melting Solid or Liquid | [color ]
White to yellow | [BRN ]
6593534 | [CAS DataBase Reference]
148547-19-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HS Code ]
29163990 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless low melting solid | [Uses]
Methyl 4-bromo-3-methylbenzoate may be used in the preparation of:
- 4-bromo-3-vinylbenzoic acid
- 4-bromo-3-(methylphenyl)methanol
- methyl (E)-4-bromo-3-[(phenylmethoxyimino)methyl]benzoate
It may be used as a starting material in the total synthesis of (-)-martinellic acid. | [General Description]
Methyl 4-bromo-3-methylbenzoate, an aromatic ester, undergoes Suzuki coupling with 2-chloroboronic acid to afford the corresponding biaryl. |
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