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ChemicalBook--->CAS DataBase List--->1445085-87-9

1445085-87-9

1445085-87-9 Structure

1445085-87-9 Structure
IdentificationBack Directory
[Name]

DavePhos-Pd-G3
[CAS]

1445085-87-9
[Synonyms]

DavePhos-Pd-G3 95%
DavePhos-Pd-G3 AldrichCPR
DavePhos Pd G3 / Methanesulfonato 2-dicyclohexylphosphino-2-(N,N-
[2-(dicyclohexylphosphino)-2-(N,N-dimethylamino)-1,1-biphenyl]-2-(2-amino-1,1-biphenyl)]palladium(II) methanesulfonate
Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
DavePhos Pd G3 / Methanesulfonato 2-dicyclohexylphosphino-2-(N,N-dimethylamino)biphenyl(2′-amino-1,1′-biphenyl-2-yl) palladium(II)
Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) CH2Cl2 adduct
Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-diMethylaMino)-1,1'-biphenyl](2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) CH2Cl2 adduct [DavePhos Palladacycle]
Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) CH2Cl2 adduct,[DavePhos Palladacycle Gen. 3]
METHANESULFONATO[2-(DICYCLOHEXYLPHOSPHINO)-2'-(N,N-DIMETHYLAMINO)-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)CH2CL2ADDUCT,MIN.98%[DAVEPHOSPALLADACYCLEGEN.3]
Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-diMethylaMino)-1,1'-biphenyl](2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) CH2Cl2 adduct, Min. 98% [DavePhos Palladacycle]
[Molecular Formula]

C39H49N2O3PPdS
[MDL Number]

MFCD27978422
[MOL File]

1445085-87-9.mol
[Molecular Weight]

763.29
Chemical PropertiesBack Directory
[Melting point ]

183-200°C (decomp)
[form ]

Powder
[color ]

white
Safety DataBack Directory
[Symbol(GHS) ]


GHS08
[Signal word ]

Warning
[Hazard statements ]

H351
[Precautionary statements ]

P201-P202-P280-P308+P313-P405-P501
Hazard InformationBack Directory
[Uses]

Pd precatalyst for cross-coupling
[General Description]

DavePhos-Pd-G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solutions and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.
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