| Identification | More | [Name]
2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER | [CAS]
14337-43-0 | [Synonyms]
1-ETHYL OXALYL CHLORIDE 2-OXIME
2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER
AKOS MSC-0743
ALPHA-CHLOROGLYOXALIC ACID ETHYL ESTER OXIME
ETHYL 2-CHLORO-2-(HYDROXYIMINO)ACETATE
ETHYL CHLOROOXIMIDOACETATE
ETHYL CHLOROOXIMINOACETATE
ETHYLCHLOROXIMIDOACETATE
TIMTEC-BB SBB009890
ZERENEX ZX011529
2-CHLORO-2-HYDROXYIMINACETIC ACID ACID ETHYL ESTER
2-chloro-2-hydroxyiminocetic
CHLOROOXIME
2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER 99+%
Ethyl chloro(hydroxyimino)acetic acid
2-(Hydroxyimino)-2-chloroacetic acid ethyl ester
Chloro(hydroxyimino)acetic acid ethyl ester
Ethylchloroximide acetate
Hydroxyiminochloroacetic acid ethyl ester
α-Chloroglyoxalic acid ethyl ester oxime | [EINECS(EC#)]
604-347-4 | [Molecular Formula]
C4H6ClNO3 | [MDL Number]
MFCD00010209 | [Molecular Weight]
151.55 | [MOL File]
14337-43-0.mol |
| Chemical Properties | Back Directory | [Melting point ]
70-76 °C (lit.) | [Boiling point ]
230.5±23.0 °C(Predicted) | [density ]
1.36±0.1 g/cm3(Predicted) | [storage temp. ]
2-8°C
| [solubility ]
soluble in Methanol | [form ]
powder to crystal | [pka]
7.60±0.10(Predicted) | [color ]
White to Almost white | [Sensitive ]
Moisture Sensitive/Lachrymatory | [BRN ]
606193 | [CAS DataBase Reference]
14337-43-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R42/43:May cause sensitization by inhalation and skin contact .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 3335 | [WGK Germany ]
3
| [F ]
10-19-21 | [HS Code ]
29280000 |
| Hazard Information | Back Directory | [Chemical Properties]
off-white solid | [Uses]
Ethyl 2-chloro-2-(hydroxyimino)acetate has been used:
- in the preparation of (+)-and (?)-Δ2-isoxazolines
- in the synthesis of CIP-AS (?), a chiral amino acid structurally related to glutamic acid, potential agonist at the ionotropic (±±)-2-amino-3-(3-hydroxy-5-methylisoxazol-4-yl)propionic acid (AMPA)-kainate receptors
- to generate ethoxycarbonylformonitrile oxide, in situ by treatment with sodium bicarbonate
- to prepare N-azirdinyloximes which on treatment with scandium triflate (418218) provide dihydro-oxadiazines
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