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ChemicalBook--->CAS DataBase List--->140-56-7

140-56-7

140-56-7 Structure

140-56-7 Structure
IdentificationMore
[Name]

Fenaminosulf
[CAS]

140-56-7
[Synonyms]

4-DIMETHYLAMINOBENZENEDIAZOSULFONIC ACID SODIUM SALT
4-DIMETHYLAMINOPHENYLDIAZOSULFONIC ACID SODIUM SALT
BAYER 22555
DAPA
Dexon
DEXON (TM)
Dexoxon
Diazoben
FENAMINOSULF
P-DIMETHYLAMINOBENZENEDIAZO-SULFONIC ACID, SODIUM SALT
SODIUM 4-DIMETHYLAMINOBENZENEDIAZOSULFONATE
SODIUM 4-DIMETHYLAMINOBENZENEDIAZO SULPHONATE
Sodium p(dimethylamino)benzenediazo sulfonate
(4-(dimethylamino)phenyl)diazenesulfonicacid,sodiumsalt
(4-(dimethylamino)phenyl)-diazenesulfonicacisodiumsalt
4-((dimethylamino)phenyl)diazenesulfonicacid,sodiumsalt
4-((dimethylamino)phenyl)diazenesulphonicacid,sodiumsalt
4-(dimethylamino)phenyl)diazenesulfonate
4-dimethylaminobenzenediazosulfonic*acidsodium
4-dimethylaminobenzenediazosulphonicacid,sodiumsalt
[EINECS(EC#)]

205-419-4
[Molecular Formula]

C8H10N3NaO3S
[MDL Number]

MFCD00059900
[Molecular Weight]

251.24
[MOL File]

140-56-7.mol
Chemical PropertiesBack Directory
[storage temp. ]

−20°C
[solubility ]

DMSO (Slightly), Methanol (Slightly)
[Water Solubility ]

Slightly soluble in water
[form ]

neat
[color ]

Light yellow to Brown
[BRN ]

4170376
[Stability:]

Hygroscopic
[CAS DataBase Reference]

140-56-7(CAS DataBase Reference)
[IARC]

3 (Vol. 8, Sup 7) 1987
[EPA Substance Registry System]

140-56-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

R21:Harmful in contact with skin.
R25:Toxic if swallowed.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 2811 6.1/PG 3
[WGK Germany ]

3
[RTECS ]

CZ1750000
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29270000
[Safety Profile]

Poison by ingestion, intravenous, and intraperitoneal routes. Experimental teratogenic effects. Human mutation data reported. Questionable carcinogen, A fungicide. When heated to decomposition it emits very toxic fumes of NOx, Na2O, and SOx
[Hazardous Substances Data]

140-56-7(Hazardous Substances Data)
[Toxicity]

bird - wild,LD50,oral,18mg/kg (18mg/kg),Toxicology and Applied Pharmacology. Vol. 21, Pg. 315, 1972.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium nitrite-->Iron-->Sodium sulfite-->N,N-Dimethylaniline-->N,N-Dimethyl-1,4-phenylenediamine
Hazard InformationBack Directory
[General Description]

Yellow-brown crystals or brown powder.
[Reactivity Profile]

Aqueous solutions are sensitive to exposure to light.
[Air & Water Reactions]

Dust may form an explosive mixture in air. Water soluble.
[Fire Hazard]

Flash point data are not available for this compound. FORMULATED FENAMINOSULF is probably combustible.
[Description]

Introduced in 1955, fenaminosulf (1; Lesan; Dexon) was one of the first selective, systemic fungicides. It is active against Phycomycetes such as Pythium, Phytophthora, and Aphanomyces but has little or no effect on higher fungi belonging to the Ascomycetes or Basidiomycetes. Fenaminosulf has a relatively high water solubility (20,000 mgL-1), a feature often associated with fungicides that specifically inhibit Oomycetes (3). Another important physicochemical property is photolytic instability, one of the reasons that fenaminosulf was developed as a seed dressing and soil fungicide (4).
As a consequence of acute toxicity , limited spectrum, and photo-instability, the use of fenaminosulf decreased (4), and it is now listed in The Pesticide Manual (5) among products that have been superseded. Although no longer used, it is included here for completeness, being the only example of a commercial fungicide that acts on complex I.
During its period of use, fenaminosulf, as wettable powder (WP), dust, or granular formulations, was employed as a seed dressing and soil-applied fungicide to control damping off and foot/root rots. Fenaminosulf-based products were used on a range of plants including vegetables, field crops, ornamentals, and turf.
[Uses]

Used in biological and pharmacological studies including:• ;Cloning and characterization of GABA transporter1• ;Activity of anti-RSV carbonucleosides2• ;Inhibition by fungicides of urea hydrolysis and nitrification of urea nitrogen in soil3
[Definition]

ChEBI: Fenaminosulf is an organic molecular entity.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Fenaminosulf(140-56-7).msds
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