| Identification | More | [Name]
1-Methyl-2-imidazolecarboxaldehyde | [CAS]
13750-81-7 | [Synonyms]
1-METHYL-1H-IMIDAZOLE-2-CARBALDEHYDE
1-METHYL-2-IMIDAZOLECARBOXALDEHYDE
1-METHYLIMIDAZOLE-2-CARBOXALDEHYDE
TIMTEC-BB SBB004338
Imidazole-2-carboxaldehyde, 1-methyl-
1-Methyl-1H-Imidazole-2-Carbal
1-METHYL-2-IMIDAZOLECARBOXALDEHYDE 98%
1-Methyl-1H-imidazole-2-carbaldehyde ,98% | [EINECS(EC#)]
627-478-9 | [Molecular Formula]
C5H6N2O | [MDL Number]
MFCD01321308 | [Molecular Weight]
110.11 | [MOL File]
13750-81-7.mol |
| Chemical Properties | Back Directory | [Appearance]
White to yellow crystalline mass, | [Melting point ]
36-39 °C (lit.) | [Boiling point ]
70-74 °C/1 mmHg (lit.) | [density ]
1.2111 (rough estimate) | [refractive index ]
1.5090 (estimate) | [Fp ]
215 °F
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Liquid | [pka]
4.17±0.25(Predicted) | [color ]
Clear colorless to yellow | [Water Solubility ]
Soluble in water. | [Sensitive ]
Air Sensitive | [Detection Methods]
HPLC | [InChIKey]
UEBFLTZXUXZPJO-UHFFFAOYSA-N | [CAS DataBase Reference]
13750-81-7(CAS DataBase Reference) | [NIST Chemistry Reference]
1H-imidazole-2-carboxaldehyde, 1-methyl-(13750-81-7) | [Storage Precautions]
Store under nitrogen |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [HazardClass ]
IRRITANT | [HS Code ]
29339900 |
| Hazard Information | Back Directory | [Chemical Properties]
White to yellow crystalline mass, | [Uses]
1-Methyl-2-imidazolecarboxaldehyde may be used in the synthesis of:
- Schiff bases
- ligand N,N-dimethyl-N′-(1-methylimidazole-2-ylmethyl)-ethylenediamine
- [(bis(1-methylimidazol-2-yl)methyl)(2-(pyridyl-2-yl)ethyl)amine]
| [Uses]
It is an important raw material and intermediate used in organic synthesis, Pharmaceuticals, agrochemicals and dyestuffs. | [Synthesis Reference(s)]
Journal of Medicinal Chemistry, 26, p. 121, 1983 DOI: 10.1021/jm00356a001 | [General Description]
1-Methyl-2-imidazolecarboxaldehyde is a heterocyclic building block. It affords tripodal ligands on condensation reaction with tris-(2-aminoethyl)amine (tren). These tripodal ligands react with iron(III) salts in the presence of air to afford iron(II) complexes. Its vibrational spectral studies have been reported. |
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