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ChemicalBook--->CAS DataBase List--->1353658-81-7

1353658-81-7

1353658-81-7 Structure

1353658-81-7 Structure
IdentificationBack Directory
[Name]

Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)
[CAS]

1353658-81-7
[Synonyms]

PCy3 Pd G2
PCy3 Palladacycle Gen.2
Tricyclohexylphosphine Pd G2
Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II)
Chloro[(tricyclohexylphosphine)(2'-aminobiphenyl-2-yl)palladium(II)
Chloro[(tricyclohexylphosphine)(2'-aminobiphenyl-2-yl)palladium(II) / PCy3 Pd G2
(SP-4-3)-[2'-(Amino)[1,1'-biphenyl]-2-yl]chloro(tricyclohexylphosphine)palladium
(SP-4-3)-[2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro(tricyclohexylphosphine)palladium
Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) ISO 9001:2015 REACH
[Molecular Formula]

C30H42ClNPPd+2
[MDL Number]

MFCD21363051
[MOL File]

1353658-81-7.mol
[Molecular Weight]

589.508
Chemical PropertiesBack Directory
[Melting point ]

244-246 °C
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
Hazard InformationBack Directory
[Uses]

PCy3 Pd G2 is a monophosphine-coordinated 2-phenylaniline-based palladacycle complex that can be used as a precatalyst:
  • To prepare diarylmethanes by Suzuki cross-coupling reaction with heterocyclic-chloromethyl derivatives with aryl/heteroaryl boronic acids.
  • To synthesize poly(arylene)s by the Suzuki cross-coupling polymerization reaction between aryl dihalides and aryldiboronic acids.
  • In the C-H bond functionalization reactions.

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