Identification | Back Directory | [Name]
(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl | [CAS]
134484-36-9 | [Synonyms]
(S)-MOP (S)-(-)-MOP 98% (S)-MOP (S)-2-Diphenyphosphino-2'-methoxyl-1,1'-biphthyl (S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl (S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL (S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL (S)-(-)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL (S)-(2'-Methoxy[1,1'-binaphthalen]-2-yl)diphenyl-phosphine (S)-(-)-2-(Diphenylphosphino)-2'-Methoxy-1,1'-binaphthyl (S)-MOP [(S)-2'-Methoxy[1,1'-binaphthalen]-2-yl]diphenylphosphine,99%e.e. (S)-(-)-(DIPHENYLPHOSPHINO)-2''-METHOXY-1,1''-BINAPHTHYL (S)-MOP (S)-(-)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl,99%(S)-MOP | [Molecular Formula]
C33H25OP | [MDL Number]
MFCD00269686 | [MOL File]
134484-36-9.mol | [Molecular Weight]
468.52 |
Chemical Properties | Back Directory | [Melting point ]
175-179°C | [alpha ]
-67° ±2° (c 1, toluene) | [Boiling point ]
584.1±38.0 °C(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
almost transparency in Toluene | [form ]
Powder | [color ]
white | [Sensitive ]
air sensitive |
Questions And Answer | Back Directory | [Reaction]
- Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols.
- Ligand for palladium-catalyzed asymmetric reduction of allylic esters.
- Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes.
- Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins.
|
|
|