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ChemicalBook--->CAS DataBase List--->134098-61-6

134098-61-6

134098-61-6 Structure

134098-61-6 Structure
IdentificationMore
[Name]

Fenpyroximate
[CAS]

134098-61-6
[Synonyms]

1,1-dimethylethyl (e)-4-(((((1,3-dimethyl-5-phenoxy-1h-pyrazol-4-yl)methylene)amino)oxy)methyl)benzoate
4-[[[[(1,3-Dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino]oxy]methyl]-benzoic acid 1,1-dimethylethyl ester
DANITORON
DANITRON
FENPYROXIMATE
KIRON
ORTUS
PAMANRIN
tert-butyl (e)-4-(((((1,3-dimethyl-5-phenoxy-1h-pyrazol-4-yl)methylene)amino)oxy)methyl)benzoate
1,1-dimethylethylester,(e)-)methyl)
4-(((((1,3-dimethyl-5-phenoxy-1h-pyrazol-4-yl)methylene)amino)oxy)methyl)-,1,1-dimethylethylester,benzoicaci
benzoicacid,4-(((((1,3-dimethyl-5-phenoxy-1h-pyrazol-4-yl)methylene)amino)oxy
nni850
t-butyl(e)-alpha-(1,3-dimethyl-5-phenoxypyrazol-4-ylmethyleneaminooxy)-p-tol
uate
Danitron,Ortus
E-1,1-dimethylethyl 4-(((1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl) methylene) amino) oxy methyl benzoate
fenproximate
tert-butyl(E)-α-(1,3-dimethyl-5-phenoxy-pyrazol-4-ylmethyleneaminoxy)-ptoluate
Fenbpyroximate
[Molecular Formula]

C24H27N3O4
[MDL Number]

MFCD00274596
[Molecular Weight]

421.49
[MOL File]

134098-61-6.mol
Chemical PropertiesBack Directory
[Melting point ]

101.1-102.4°
[Boiling point ]

546.2±60.0 °C(Predicted)
[density ]

1.25g/cm3
[storage temp. ]

Store at -20°C
[solubility ]

Chloroform: Slightly soluble,Methanol: Slightly soluble
[Water Solubility ]

Insoluble in water
[form ]

powder to crystal
[pka]

1.58±0.10(Predicted)
[color ]

White to Light yellow to Light orange
[Stability:]

Light Sensitive
[LogP]

6.443 (est)
[CAS DataBase Reference]

134098-61-6(CAS DataBase Reference)
[EPA Substance Registry System]

134098-61-6(EPA Substance)
Safety DataBack Directory
[RIDADR ]

UN3082 (liquid)
[HS Code ]

29331990
[Hazardous Substances Data]

134098-61-6(Hazardous Substances Data)
[Toxicity]

LD50 in male, female rats (mg/kg): 480, 245 orally; >2000, >2000 dermally; LC50 (48hr) in carp: 6.1 mg/l; LC50 (3hr) in daphnia pulex: 85 mg/l (Konno)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydroxylamine hydrochloride-->Ethyl acetoacetate-->Methylhydrazine-->Formamide-->Potassium hydroxide solution-->Pyrazole-->4-Bromomethylbenzoic acid-->1,3-Dimethyl-5-pyrazolone-->FORMOXIME
Hazard InformationBack Directory
[Uses]

Acaricide.
[Definition]

ChEBI: Fenpyroximate is a pyrazole acaricide and a tert-butyl ester. It has a role as a mitochondrial NADH:ubiquinone reductase inhibitor. It derives from a hydride of a 1H-pyrazole.
[Agricultural Uses]

Acaricide, Miticide, Insecticide: Used to control spider mites in greenhouses.
[Trade name]

AKARI®; HOE® 555-02A; NNI®-850; SEQUEL®
[Metabolic pathway]

When fenpyroximate is administered orally to rats, radiocarbons from 14C-fenpyroximate are rapidly and almost completely excreted in the urine and feces within 72 h, and fenyproximate seems to be metabolized via oxidation of the tert-butyl group and methyl group at the 3-position in the pyrazole ring, p- hydroxylation in the phenoxy moiety, N-demethylation, hydrolysis of the tert-butyl ester, cleavage of the oxime ether bond, and/or E/Z isomerization. In soils, 12 degradation products are identified, and in sterilized soils the degradation of fenpyroximate and CO2, evolution are negligible. Fenpyroximate degrades through hydrolysis of tert-butyl ester, isomerization or cleavage of the oxime ether, N-demethylation, oxidation of the methyl group at the 3-position on the pyrazole ring, and hydroxylation of the phenoxy ring, and is finally mineralized to CO2 and/or bound to soil organic matter.
Spectrum DetailBack Directory
[Spectrum Detail]

Fenpyroximate(134098-61-6)1HNMR
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