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ChemicalBook--->CAS DataBase List--->109-89-7

109-89-7

109-89-7 Structure

109-89-7 Structure
IdentificationMore
[Name]

Diethylamine
[CAS]

109-89-7
[Synonyms]

AKOS BBS-00004389
DEA
DIETHYLAMINE
N-ETHYLETHANAMINE
n,n-diethylamine
(C2H5)2NH
ai3-24215
detn
Diaethylamin
Diethamine
Diethylamin
Dietilamina
Dwuetyloamina
dwuetyloamina(polish)
ethanamine,n-ethyl
ethanamine,n-ethyl-
N,N-Diethylamin
n-ethyl-ethanamin
N-Ethylethanemine
DIISOPROPYLAMINE, >=99.5%
[EINECS(EC#)]

203-716-3
[Molecular Formula]

C4H11N
[MDL Number]

MFCD00009032
[Molecular Weight]

73.14
[MOL File]

109-89-7.mol
Chemical PropertiesBack Directory
[Description]

Diethylamine is a colourless, strongly alkaline, fish odour liquid, and highly inflammable. It has an ammonia-like odour and is completely soluble in water. On burning, diethylamine releases ammonia, carbon monoxide, carbon dioxide, and nitrogen oxides. It is incompatible with several chemical substances such as strong oxidisers, acids, cellulose nitrate, some metals, and dicyanofuroxan. N-nitrosamines, many of which are known to be potent carcinogens, may be formed when diethylamine comes in contact with nitrous acid, nitrates, or atmospheres with high nitrous oxide concentrations. The applications of Diethylamine are numerous. Diethylamine is used in the production of pesticides. It is used in a mixture for the production of DEET which goes into the repellents that are found readily in supermarkets for general use. Diethylamine is also mixed with other chemicals to form Diethylaminoethanole, which is used mainly as a corrosion inhibitor in water treatment facilities as well as production of dyes, rubber, resins, and pharmaceuticals. Diethylamine is also used in manufacture of basic chemicals and pharmaceuticals.
[Appearance]

Colorless liquid
[Melting point ]

-50 °C (lit.)
[Boiling point ]

55 °C (lit.)
[density ]

0.707 g/mL at 25 °C(lit.)
[vapor density ]

2.5 (vs air)
[vapor pressure ]

14.14 psi ( 55 °C)
[refractive index ]

n20/D 1.385(lit.)
[Fp ]

−20 °F
[storage temp. ]

Store at RT
[solubility ]

H2O: soluble1M at 20°C, clear, colorless
[form ]

Liquid
[pka]

11.02(at 40℃)
[color ]

Clear colorless
[Odor]

Ammoniacal; sharp, fishy.
[PH]

13 (100g/l, H2O, 20℃)
[PH Range]

Strong alkaline
[Relative polarity]

0.145
[Stability:]

Stable. Highly flammable. Incompatible with strong oxidizing agents.
[explosive limit]

2.0-11.8%(V)
[Odor Threshold]

0.048ppm
[Odor Type]

ammoniacal
[Water Solubility ]

soluble
[Sensitive ]

Air Sensitive
[Merck ]

14,3111
[BRN ]

605268
[Henry's Law Constant]

2.56(x 10-5 atm?m3/mol) at 25 °C (Christie and Crisp, 1967)
[Dielectric constant]

3.7(20℃)
[Exposure limits]

NIOSH REL: TWA 10 ppm (30 mg/m3), STEL 25 ppm (75 mg/m3), IDLH 200 ppm; OSHA PEL: TWA 25 ppm; ACGIH TLV: TWA 5 ppm, STEL 15 ppm (adopted).
[InChIKey]

HPNMFZURTQLUMO-UHFFFAOYSA-N
[LogP]

0.58 at 20℃
[CAS DataBase Reference]

109-89-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethanamine, N-ethyl-(109-89-7)
[EPA Substance Registry System]

109-89-7(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

Diethylamine is a colorless, strongly alkaline, highly inflammable, liquid. It is completely soluble in water. On burning, diethylamine releases ammonia, carbon monoxide, carbon dioxide, and nitrogen oxides. It is incompatible with several chemical substances, such as strong oxidizers, acids, cellulose nitrate, some metals, and dicyanofuroxan. N-nitrosamines, many of which are known to be potent carcinogens, may be formed when diethylamine comes in contact with nitrous acid, nitrates, or atmospheres with high nitrous oxide concentrations. It has several applications in industries, such as organic synthesis of resins, as rubber accelerator, pharmaceuticals, pesticides, dyes, electroplating operations, and as a polymerization inhibitor.
[General Description]

A clear colorless liquid with an ammonia-like odor. Density 5.9 lb/gal. Flash point-15°F. A respiratory irritant. Corrosive to the eyes and skin. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion.
[Reactivity Profile]

DIETHYLAMINE(109-89-7) is strongly alkaline. Incompatible with strong oxidizing agents and with strong acids. Violent reactions occur with sulfuric acid. Causes ignition on contact with cellulose nitrate. Explodes on contact with dicyanofurazan or dicyanofuroxan. Attacks some forms of plastics, rubber and coatings.
[Air & Water Reactions]

Highly flammable. Soluble in water. Sensitive to heat. May be sensitive to prolonged exposure to air.
[Health Hazard]

Exposures to diethylamine cause adverse health effects. The symptoms of toxicity include irritation of skin, eyes, and mucous membrane. The acute oral LD50 and acute dermal LD50 in rats and rabbits are 540 and 580 mg/kg, respectively, and the acute inhalation LC50 (4 h) in rats is 4000 ppm. The pathomorphological changes caused by diethylamine include lungs, liver, and kidneys, cellular infi ltration, bronchopneumonia, parenchymatous degeneration, and nephritis.
[Health Hazard]

Irritation and burning of eyes, skin, and respiratory system. High concentration of vapor can cause asphyxiation.
[Physical properties]

Colorless liquid with a fishy, ammonia-like odor. Experimentally determined detection and recognition odor threshold concentrations were 60 μg/m3 (20 ppbv) and 180 μg/m3 (60 ppbv), respectively (Hellman and Small, 1974). Diethylamine is a very strong base in aqueous solution (pKb = 3.0). Its chemistry is governed by the unshared electron pair on the nitrogen, thus it tends to react with acids to form salts.

[Occurrence]

Diethylamine occurs in low concentrations in food and other biological materials. Concentrations (in p.p.m.) in fresh products include: spinach (15), apples (3), butterbeans (2.4), shelled peas (0.1), bean salad (1.5) and red cabbage (2.4) (HSDB 1989). Pickled vegetables contain 0-3.2 p.p.m. diethylamine while concentrations (in p.p.m.) in other materials include herring (0-5.2), barley (5.7), hops (3.1), boiled beef (2), tobacco leaf (0.1-35) and cigarette smoke concentrate (0-0.4). Interest in the occurrence of diethylamine in foods arises in part because of its possible formation of a carcinogenic N-nitroso derivative (Neurath et al 1977). Diethylamine has been reported in the exhaust from a gasoline engine (Hampton et al 1982).
[Uses]

Diethylamine is manufactured by heating ethyl chloride and alcoholic ammonia under pressure or by hydrogenation of aziridines in the presence of catalysts. DEA is used as a solvent, as a rubber accelerator, in the organic synthesis of resins, dyes, pesticides, and pharmaceuticals, in electroplating, and as a polymerization inhibitor. Other applications include uses as a corrosion inhibitor. It was reported noneffective as a skin depigmentator.
[Uses]

In flotation agents, resins, dyes, resins, pesticides, rubber chemicals, and pharmaceuticals; selective solvent; polymerization and corrosion inhibitors; petroleum chemicals; electroplating; organic synthesis.
[Uses]

In the rubber and petroleum industry; in flotation agents; in resins, dyes, pharmaceuticals
[Definition]

ChEBI: A secondary aliphatic amine where both N-substituents are ethyl.
[Production Methods]

Diethylamine is produced using the three methods also used for the manufacture of ethylamine with very slight modification. The most widely used method is the passing of ammonia and ethanol over a catalyst such as alumina or silica (Schweizer et al 1978). Diethylamine can be separated from the mixture by selective distillations and extractions. This secondary amine can also be produced by the other two methods which involve: 1) passing ammonia, ethanol, and hydrogen over a dehydrogenation catalyst; and 2) passing ammonia and an aldehyde or ketone and hydrogen over a hydrogenation catalyst. U.S. production in 1984 is estimated at 19.7 million pounds (HSDB 1989).
[Flammability and Explosibility]

Highlyflammable
[Chemical Reactivity]

Reactivity with Water No reaction; Reactivity with Common Materials: No hazardous reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with water; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
[Industrial uses]

Diethylamine, like many of the other short chain aliphatic amines, has achieved widespread industrial use as an intermediate in the manufacture of a number of commercial products. Among these are included insecticides, pharmaceuticals, textile finishing agents, and corrosion inhibitors (Hawley 1981; Schweizer et al 1978). It is used as a polymerization inhibitor and/or catalyst in the polymer industry and in the manufacture of surfactants and rubber processing accelerators. This amine also is useful as a depilatory agent for animal skins, as a selective solvent for the removal of impurities from oils, fats, and waxes, and as a flotation agent in the petroleum industry (NIOSH/OSHA 1981; HSDB 1989).
[Toxicology]

Exposure to low vapor concentrations are reported to transiently impair vision in humans (reduction of sensitivity to light): no-effect threshold 0.022 – 0.028 mL/m3 ( 0.08mg/m3 ). The odor threshold in air is ca. 0.02 – 0.3 mL/m3 ( 0.9 mg/m3 ). Transient physiological effects in rats after 90-d exposure to vapors were reported to already be visible at 0.37 – 4.19 mg/m3 with no effects at 0.05 mg/m3 , but with morphological, apparently reversible changes in the lung and cerebral neurons at the highest concentration. On the other hand, 50 mL/m3 (150 mg/m3 ) was the lowest concentration to show mild, but signifi- cant effects in the lung and liver of rabbits on prolonged inhalation. There were no visible signs of toxicity following exposure of rats to 25 mL/m3 (75 mg/m3 ) for 120 d, but a moderate, bronchiolar hyperplasia of lymphoid cells. It was assumed that diethylamine may exert a certain neurotoxic effect, which, however, was not confirmed by others.
[Potential Exposure]

Tumorigen,Mutagen. Primary Irritant. Diethylamine (DEA) is used in themanufacture of the following chemicals: diethyldithiocarbamate and thiurams (rubber processing accelerators);diethylaminoethanol (medicinal intermediate); diethylaminopropylamine (epoxy curing agent); N,N-diethyl-m-toluamide and other pesticides; and 2-diethylaminoethylmethacrylate. Itis used in the manufacture of several drugs.
[First aid]

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Medical observation is recommended for 24-48 h afterbreathing overexposure, as pulmonary edema may bedelayed. As first aid for pulmonary edema, a doctor orauthorized paramedic may consider administering a corticosteroid spray.
[Carcinogenicity]

No evidence of mutagenicity was seen in Ames bacterial assays.8 Diethylamine has an ammonia-like odor that is detectable at 0.13ppm.
The 2003 ACGIH threshold limit valuetime- weighted average (TLV-TWA) for diethylamine is 5ppm (15mg/m3) with a short-term excursion limit of 15ppm (45mg/m3) and an A4-not classifiable as a human carcinogen designation; there is a notation for skin absorption.
[Environmental Fate]

Photolytic. Low et al. (1991) reported that the photooxidation of aqueous secondary amine solutions by UV light in the presence of titanium dioxide resulted in the formation of ammonium and nitrate ions.
Chemical/Physical. Diethylamine reacted with NOx in the dark forming diethylnitrosamine. In an outdoor chamber, photooxidation by natural sunlight yielded the following products: diethylnitramine, diethylformamide, diethylacetamide, ethylacetamide, ozone, acetaldehyde, and peroxyacetyl nitrate (Pitts et al., 1978).
Reacts with mineral acids forming water-soluble salts (Morrison and Boyd, 1971).
[Metabolism]

Little information is available regarding the metabolism of diethylamine. The amine can be readily absorbed from the respiratory and gastrointestinal tract. It has been reported that following oral administration of diethylamine hydrochloride to humans, much of the amine was recovered in the urine (Beard and Noe 1978). This suggests that it is not readily metabolized and, therefore, may not be a substrate for monoamine oxidase. When administered intraperitoneally to rats, it was moderately inhibitory with respect to liver monoamine oxidase (Valiev 1974). Diethylamine may serve as a precursor for the formation of the reportedly carcinogenic N-nitrosoamines and, indeed, when a diethylamine containing liquid was examined for nitrosation reactions under simulated conditions of the human stomach, N-nitrosodiethylamine was formed (Ziebarth 1985).
[Shipping]

This compound requires a shipping label of“FLAMMABLE LIQUID.” It falls in Hazard Class 3 andPacking Group II.
[Purification Methods]

Dry diethylamine with LiAlH4 or KOH pellets. Reflux with, and distil it from, BaO or KOH. Convert it to the p-toluenesulfonamide and crystallise to constant melting point from dry pet ether (b 90-120o), then hydrolyse with HCl, excess NaOH is added, and the amine is passed through a column of activated alumina. Redistil the amine and dry it with activated alumina before use [Swift J Am Chem Soc 64 115 1942]. [Beilstein 4 III 313.] § A polystyrene diethylaminomethyl supported version is commercially available.
[Incompatibilities]

Forms explosive mixture with air. Mayaccumulate static electrical charges, and may cause ignitionof its vapors. Violent reaction with strong oxidizers, strongacids, cellulose nitrate. Incompatible with organic anhydrides, isocyanates, vinyl acetate, acrylates, substitutedallyls, alkylene oxides, epichlorohydrin, ketones, aldehydes,alcohols, glycols, mercury, phenols, cresols, caprolactumsolution. Attacks aluminum, copper, lead, tin, zinc, andalloys.
Safety DataBack Directory
[Hazard Codes ]

F,C
[Risk Statements ]

R11:Highly Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R35:Causes severe burns.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S29:Do not empty into drains .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S3:Keep in a cool place .
[OEB]

A
[OEL]

TWA: 10 ppm (30 mg/m3), STEL: 25 ppm (75 mg/m3)
[RIDADR ]

UN 1154 3/PG 2
[WGK Germany ]

1
[RTECS ]

HZ8750000
[F ]

10-23
[Autoignition Temperature]

594 °F
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29211990
[storage]

Diethylamine should be protected from physical damage. It should be kept stored in a cool, dry, well-ventilated location, away from incompatible chemical substances and away from fi re hazard and smoking areas. The containers should be bonded and grounded for transfer to avoid static sparks. Storage and use areas should be no smoking areas.
[Precautions]

Occupational workers and users should be very careful during the use and chemical management of diethylamine. Workers should wear impervious protective clothing, including boots, gloves, a laboratory coat, apron or coveralls, as appropriate, to prevent skin contact. The chemical is very hazardous, corrosive, and harmful, and is a very flammable liquid and vapor. Exposures to vapor may cause fl ash fi re. It causes burns and adverse effects to the cardiovascular system. Workers should use chemical safety goggles and a full-face shield to avoid splashing of the chemical substance. An eye-wash fountain and quickdrench facilities in the work area should be maintained by the chemical management unit.
[Safety Profile]

Moderately toxic by ingestion, inhalation, and skin contact. A skin and severe eye irritant. Exposure to strong vapor can cause severe cough and chest pains. Contact with liquid can damage eyes, possibly permanently; contact with skin causes necrosis and vesciculation. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. To fight fire, use alcohol foam, CO2, dry chemical. Explodes on contact with dicyanofurazan. Violent reaction with sulfuric acid. Ignites on contact with cellulose nitrate of sufficiently high surface area. When heated to decomposition it emits toxic fumes of NOx. See also MINES.
[Hazardous Substances Data]

109-89-7(Hazardous Substances Data)
[Toxicity]

LD50 orally in rats: 540 mg/kg (Smyth)
[IDLA]

200 ppm
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Ammonia-->Hydrogen-->2-Ethylaniline-->2-(Ethylamino)ethanol
[Preparation Products]

4-phenyl-1-(p-tolylsulphonyl)piperidine-4-carboxylic acid-->Montelukast-->4'-Iodoacetophenone-->4,6-DIMETHYL-1H-PYRAZOLO[3,4-B]PYRIDIN-3-AMINE-->2-AMINO-6-METHYL-4,5,6,7-TETRAHYDRO-1-BENZOTHIOPHENE-3-CARBONITRILE-->2-AMINO-5,6-DIHYDRO-4H-CYCLOPENTA[B]THIOPHENE-3-CARBONITRILE-->1,4,6-Trimethyl-1H-pyrazolo[3,4-b]pyridin-3-ylamine ,97%-->7-(DIETHYLAMINO)-5-METHYL-S-TRIAZOLO[1,5-A]PYRIMIDINE-->Diethylcarbamyl chloride-->Benzyl cinnamate-->2-AMINO-4,5,6,7-TETRAHYDRO-1-BENZOTHIOPHENE-3-CARBONITRILE-->2-AMINO-4,5-DIMETHYL-THIOPHENE-3-CARBONITRILE-->3-(DIETHYLAMINO)PROPANOIC ACID-->Benzyl salicylate-->5-AMINO-3-METHYL-THIOPHENE-2,4-DICARBOXYLIC ACID DIMETHYL ESTER-->(5-BROMO-PYRIMIDIN-2-YL)-DIETHYL-AMINE-->3-Cyano-4,6-dimethyl-2-hydroxypyridine-->DIETHYLCARBAMAZINE-->Fast Red ITR-->2-(N,N-DIETHYLAMINOCARBONYL)PHENYLBORONIC ACID-->Ethyl ziram-->Etamsylate-->2-Chloro-3-cyano-4,6-dimethylpyridine-->Lidocaine hydrochloride-->1,1-diethylguanidine hydrochloride-->N,N-Diethylcyanoacetamide-->Procaine hydrochloride-->BIS(DIETHYLAMINO)CHLOROPHOSPHINE-->Diethylamine hydrochloride-->DIETHYLCYANAMIDE-->ESFENVALERATE FREE ACID METABOLITE-->FAST RED SALT ITR-->3-Diethylaminopropylamine-->coating adhesive tiemao 102-->N,N-Diethyl-m-toluamide-->N,N-DIETHYLNICOTINAMIDE-->Disulfiram-->DIETHYLAMMONIUM DIETHYLDITHIOCARBAMATE-->N,N-Diethyl-2-chloropropionamide-->TRIS(DIETHYLAMINO)PHOSPHINE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

DEA(109-89-7).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Diethylamine(109-89-7)MS
Diethylamine(109-89-7)1HNMR
Diethylamine(109-89-7)13CNMR
Diethylamine(109-89-7)IR1
Diethylamine(109-89-7)IR2
Diethylamine(109-89-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Diethylamine, extra pure, 99+%(109-89-7)
[Alfa Aesar]

Diethylamine, 99+%(109-89-7)
[Sigma Aldrich]

109-89-7(sigmaaldrich)
[TCI AMERICA]

Diethylamine,>99.0%(GC)(109-89-7)
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