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ChemicalBook--->CAS DataBase List--->1019-71-2

1019-71-2

1019-71-2 Structure

1019-71-2 Structure
IdentificationBack Directory
[Name]

Chlorodi(p-tolyl)phosphine, 95%
[CAS]

1019-71-2
[Synonyms]

orodi(p-toL
Di-p-tolylchlorophosphine
chlorodi-p-tolylphosphane
Chlorodi(p-tolyl)phosphine, 95%
Di(p-tolyl)phosphinous Chloride
Chlorodi(p-tolyl)phosphine
Chlorobis(4-methylphenyl)phosphine
chloro-bis(4-methylphenyl)phosphane
Phosphinous chloride, P,P-bis(4-methylphenyl)-
P,P-Bis(4-methylphenyl)-phosphinous chloride, Chlorodi-p-tolylphosphine
[EINECS(EC#)]

202-848-9
[Molecular Formula]

C14H14ClP
[MDL Number]

MFCD01630844
[MOL File]

1019-71-2.mol
[Molecular Weight]

248.69
Chemical PropertiesBack Directory
[Boiling point ]

180-184℃/10mm
[density ]

1.1 g/mL at 25 °C
[refractive index ]

n20/D1.501
[storage temp. ]

Sealed in dry,2-8°C
[Water Solubility ]

Reacts with water.
[Sensitive ]

Air & Moisture Sensitive
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

14-34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 3265 8 / PGIII
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

II
Hazard InformationBack Directory
[Uses]

Reactant for synthesis of:
  • Palladium catalysts for C-C bond forming cross-coupling reactions
  • Ligands for nickel(0)-catalyzed isomerization reactions
  • Phosphinosulfonamide nickel complexes for oligomerization reactions

Reactant for:
  • Pd-catalyzed intramolecular asymmetric allylic amination and ring-closing metathesis
  • Phosphinylation reactions
[Uses]

Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.
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