| Identification | More | [Name]
Nickel sulfate hexahydrate | [CAS]
10101-97-0 | [Synonyms]
ACTIMET M
NICKEL
NICKEL(+2)SULFATE HEXAHYDRATE
NICKEL AA/ICP CALIBRATION/CHECK STANDARD
NICKEL AA SINGLE ELEMENT STANDARD
NICKEL, AAS STANDARD SOLUTION
NICKEL AA STANDARD
NICKEL, ANALYTICAL STANDARD
NICKEL ATOMIC ABSORPTION SINGLE ELEMENT STANDARD
NICKEL ATOMIC ABSORPTION STANDARD
NICKEL ATOMIC ABSORPTION STANDARD SOLUTION
NICKEL ATOMIC SPECTROSCOPY STANDARD
NICKEL CATALYST
NICKEL CATALYST ON KIESELGUHR
NICKEL ICP/DCP STANDARD
NICKEL ICP STANDARD
NICKEL(II) SULFATE
NICKEL(II) SULFATE HEXAHYDRATE
NICKEL(II) SULPHATE 6-HYDRATE
NICKEL MATRIX MODIFIER | [EINECS(EC#)]
231-111-4 | [Molecular Formula]
H12NiO10S | [MDL Number]
MFCD00149813 | [Molecular Weight]
262.85 | [MOL File]
10101-97-0.mol |
| Chemical Properties | Back Directory | [Appearance]
Green crystals | [Melting point ]
1453 °C(lit.) | [Boiling point ]
2732 °C(lit.) | [density ]
2,07 g/cm3 | [vapor density ]
2.07 (vs air) | [storage temp. ]
Flammables area | [solubility ]
H2O: soluble
| [form ]
wire
| [color ]
Green | [Specific Gravity]
2.07 | [PH]
4.3-4.7 (100g/l, H2O, 20℃) | [Stability:]
Stable. Efflorescent. Incompatible with strong acids, sulfur, nickel nitrate, wood, other combustibles. | [Water Solubility ]
625 g/L (20 ºC) | [Merck ]
14,6517 | [InChIKey]
RRIWRJBSCGCBID-UHFFFAOYSA-L | [CAS DataBase Reference]
10101-97-0(CAS DataBase Reference) | [EPA Substance Registry System]
10101-97-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T,Xi,N,Xn,F | [Risk Statements ]
R45:May cause cancer.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R42/43:May cause sensitization by inhalation and skin contact .
R40:Limited evidence of a carcinogenic effect.
R22:Harmful if swallowed.
R36/37:Irritating to eyes and respiratory system .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable.
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S60:This material and/or its container must be disposed of as hazardous waste .
S36/37:Wear suitable protective clothing and gloves .
S22:Do not breathe dust .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 3178 4.1/PG 2
| [WGK Germany ]
3
| [RTECS ]
WT1157000
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
28332400 | [Safety Profile]
Confirmed human
carcinogen. Poison by ingestion,
intravenous, and subcutaneous routes.
Experimental reproductive effects. Human
mutation data reported. When heated to
decomposition it emits toxic fumes of SOx.
See also NICKEL SULFATE. | [Toxicity]
LD50 in male, female rats (mg/kg): 335, 264 orally (Reagan) |
| Hazard Information | Back Directory | [General Description]
Blue or emerald-green crystalline material. Toxic and carcinogenic. Two known phases. Alpha-form (blue tetragonal) converts to beta-form (green monoclinic) at 127.9°F. Becomes blue and opaque at room temperature. Odorless. Sweet astringent taste. Somewhat efflorescent. Greenish-yellow anhydrous salt is formed at 536°F. | [Reactivity Profile]
NICKEL SULFATE HEXAHYDRATE(10101-97-0) is incompatible with strong acids, sulfur, Ni(NO3)2, wood and other combustibles. At elevated temperature undergoes violent reaction with powdered aluminum or magnesium. When heated to decomposition NICKEL SULFATE HEXAHYDRATE(10101-97-0) emits very toxic fumes of oxides of sulfur [Lewis, 3rd ed., 1993, p. 918]. | [Air & Water Reactions]
Water soluble. | [Fire Hazard]
Flash point data for this chemical are not available. NICKEL SULFATE HEXAHYDRATE is probably combustible. | [Chemical Properties]
Nickel sulphate hexahydrate is available as odourless, blue-green crystals. It is stable at room temperature in closed containers under normal storage and handling conditions and incompatible with strong acids and strong oxidising agents. On decomposition, nickel (II) sulphate hydroxylate releases oxides of sulphur, irritating and toxic fumes and gases, and nickel oxide.
| [Uses]
Nickel sulfate hexahydrate is a source of nickel metal, a common allergen present in various alloys, electroplated metal, earrings, lipstick holders, watches, buttons,
zippers, rings, utensils, tools, instruments, batteries, machinery parts, working solutions of metal cutting fluids, nickel plating for
alloys, coins, pigments, dentures, orthopedic plates, keys, scissors, razors, spectacle frames, kitchenware etc. May produce erythema
multiforme like eruptions. | [Uses]
Nickel sulfate hexahydrate is mainly used in Ni plating, as mordant in dyeing and in printing textiles, as a blackening agent for zinc and brass and in the fabrication of organic nickel salts. It is used as an effective catalyst for gas-phase dehydration of glycerol to acrolein. Nickel sulfate hexahydrate crystal is an efficient ultraviolet filter material. Columns used in biochemistry and molecular biology can be regenerated with nickel sulfate. It is used to prepare nickel carbonate, a precursor to pigments and nickel-based catalysts. | [Uses]
Source of nickel in standards. | [Definition]
ChEBI: A hydrate that is the hexahydrate of nickel sulfate. |
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