| Identification | More | [Name]
4-Aminodiphenylamine | [CAS]
101-54-2 | [Synonyms]
4-AMINODIPHENYLAMINE
AKOS AUF02008
AZOIC DIAZO COMPONENT 22
DIPHENYL BLACK N-PHENYL-P-PHENYLENE-DIAMINE
LABOTEST-BB LT00038663
N-PHENYL-1,4-PHENYLENEDIAMINE
N-PHENYL-P-PHENYLENEDIAMINE
P-AMINODIPHENYLAMINE
VARIAMINE BLUE RT
Variamine Blue RT Base
4-(Phenylamino)aniline
4-amino-diphenylamin
4-Benzenediamine,N-phenyl-1
Acna Black DF Base
acnablackdfbase
Azosalt R
azosaltr
Benzenediamine, N-phenyl-
blackbasep
C.I. 76085 | [EINECS(EC#)]
202-951-9 | [Molecular Formula]
C12H12N2 | [MDL Number]
MFCD00007850 | [Molecular Weight]
184.24 | [MOL File]
101-54-2.mol |
| Chemical Properties | Back Directory | [Appearance]
Dark grey flake | [Melting point ]
69 °C | [Boiling point ]
354 °C
| [density ]
1.09 | [vapor pressure ]
1 hPa | [refractive index ]
1.6266 (estimate) | [Fp ]
193°C | [storage temp. ]
Store below +30°C. | [solubility ]
ethanol: soluble10mg/mL, clear, very dark red (Violet to brown to black solution) | [Colour Index ]
37240 | [form ]
Liquid | [pka]
5.20±0.10(Predicted) | [color ]
Clear | [PH]
8.9 (0.5g/l, H2O, 20℃) | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, plastics. | [Water Solubility ]
Soluble in water at 20°C 0.6g/L. Soluble in (10 mg/mL) ethanol. | [BRN ]
908935 | [Contact allergens]
This substance was formerly used as a hair dye.
Sensitization, when detected by patch testing, is relatively
low in hairdressers. | [CAS DataBase Reference]
101-54-2(CAS DataBase Reference) | [NIST Chemistry Reference]
1,4-Benzenediamine, N-phenyl-(101-54-2) | [EPA Substance Registry System]
p-Aminodiphenylamine (101-54-2) |
| Hazard Information | Back Directory | [Chemical Properties]
Dark grey flake | [Definition]
ChEBI: An aromatic amine that is the 4-amino derivative of diphenylamine. | [General Description]
Odorless purple-black solid or flake or dark purple chips. | [Reactivity Profile]
N-PHENYL-P-PHENYLENEDIAMINE(101-54-2) is incompatible with strong oxidizers. N-PHENYL-P-PHENYLENEDIAMINE(101-54-2) is also incompatible with strong acids. N-PHENYL-P-PHENYLENEDIAMINE(101-54-2) may react with plastics. | [Air & Water Reactions]
Insoluble in water. | [Fire Hazard]
This chemical is combustible. | [Description]
p-Aminodiphenylamine hydrochloride was formerly
used as a hair dye. Sensitization, when deteeted by
patch testing, is relatively low in hairdressers. | [Uses]
4-Aminodiphenylamine is used as an oxidation dye color in hair
dyes. It is also promoted as an efficient reagent for oxidase
enzymes, including glucose, lactate, xanthine, and lysine
oxidases. | [Uses]
Dye intermediate, pharmaceuticals, photographic chemicals. | [Uses]
p-Anilinoaniline is an antioxidant that has shown to cause a reduction of NOx emissions from soybean biodiesel powered DI diesel engines but has increased CO and HC emissions. It is also used to produce dyes, pharmaceuticals, and photographic chemicals and frmerly used as a hair dye. | [Purification Methods]
It crystallises from EtOH with m 66o, and from ligroin with m 75o. It can be distilled at high vacuum. [Beilstein 13 IV 113.] |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R22:Harmful if swallowed.
R36:Irritating to the eyes.
R43:May cause sensitization by skin contact.
R42/43:May cause sensitization by inhalation and skin contact .
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/22:Harmful by inhalation and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN3077 | [WGK Germany ]
3
| [RTECS ]
ST3150000
| [F ]
8 | [Autoignition Temperature]
>500 °C | [Hazard Note ]
Irritant | [TSCA ]
Yes | [HazardClass ]
9 | [PackingGroup ]
III | [HS Code ]
29215990 | [Hazardous Substances Data]
101-54-2(Hazardous Substances Data) | [Toxicity]
LD50 orally in Rabbit: 464 mg/kg LD50 dermal Rabbit > 5000 mg/kg |
|
|