| Identification | More | [Name]
VANADIUM(IV) FLUORIDE | [CAS]
10049-16-8 | [Synonyms]
VANADIUM FLUORIDE
VANADIUM(IV) FLUORIDE
VANADIUM TETRAFLUORIDE
Vanadium(IV) fluoride 95%
Vanadium(IV)fluoride95%
Vanadium(IV) tetrafluoride | [EINECS(EC#)]
233-171-7 | [Molecular Formula]
F4V | [MDL Number]
MFCD00042554 | [Molecular Weight]
126.94 | [MOL File]
10049-16-8.mol |
| Chemical Properties | Back Directory | [Appearance]
green to brown powder | [Melting point ]
325 °C (dec.)(lit.) | [density ]
2.975 g/mL at 25 °C(lit.)
| [solubility ]
very soluble in H2O | [form ]
Powder | [color ]
Yellow to brown | [Specific Gravity]
3.15 | [Water Solubility ]
Soluble in water (blue color), acetone (deep green color), and glacial acetic acid (blue-green color) | [Sensitive ]
Moisture Sensitive | [Exposure limits]
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3; Ceiling 0.05 mg/m3 | [CAS DataBase Reference]
10049-16-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
T,Xi | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R34:Causes burns. | [Safety Statements ]
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3290 6.1/PG 2
| [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
2826199090 |
| Hazard Information | Back Directory | [Chemical Properties]
green to brown powder | [Uses]
Vanadium(IV) fluoride is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. | [Production Methods]
Freshly distilled, Dry Ice-cooled VCl4 (40 g) is added to 130 g of similarly cooled anhydrous HF contained in a reactor. A copper reflux condenser charged with a cooling mixture is then attached to the vessel, and the reaction mixture is allowed to warm slowly to 0°C. The mixture is then boiled for several hours until no further HCl evolves. The reflux condenser is then replaced by a descending condenser, and the HF is distilled off. The VF4 remaining in the reactor is freed of any traces of HF by passing a dry stream of nitrogen at 50°C. The yield is 97%, based on VCl4. The product may be stored in sealed iron or copper containers.
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| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Spectrum Chemical Manufacturing Corp.
|
| Tel: |
021-021-021-67601398-809-809-809 15221380277 |
| Website: |
www.spectrumchemical.com/oa_html/index.jsp?minisite=10020&respid=22372&language=us |
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