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88625-23-4

Pyrazinecarbonyl chloride, 5-chloro- (9CI) synthesis

7synthesis methods
36070-80-1 Synthesis
5-CHLORO-PYRAZINE-2-CARBOXYLIC ACID

36070-80-1
275 suppliers
$9.00/1g

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Yield: 100%

Reaction Conditions:

with (COCl)2;N-methyl-acetamide in dichloromethane

Steps:

Preparation of Starting Material 5-chloro-N,N-dimethylpyrazine-2-carboxamide (SM-1)
Preparation of Starting Material 5-chloro-N,N-dimethylpyrazine-2-carboxamide (SM-1) 5-chloropyrazine-2-carboxylic acid (1.00 gram, 6.31 mmol) in dichloromethane (30 ml) was treated with catalytic amount of dimethylformamide, followed by (COCl)2 (0.85 ml, 9.46 mmol). The resulting mixture was stirred over night. The reaction was concentrated in vacuo, and dried under vacuum to give desired 5-chloropyrazine-2-carbonyl chloride as solid (1.05 g, 100%).

References:

Pfizer Inc US2010/234285, 2010, A1

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