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ChemicalBook CAS DataBase List N1-(5-CHLORO-4-FLUORO-2-NITROPHENYL)ACETAMIDE
81962-58-5

N1-(5-CHLORO-4-FLUORO-2-NITROPHENYL)ACETAMIDE synthesis

4synthesis methods
-

Yield:81962-58-5 90%

Reaction Conditions:

with sulfuric acid;HNO3 at -4 - 20; for 0.666667 h;

Steps:

2 4.5.2. Synthesis of N-(2-nitro-4-fluoro-5-chlorophenyl)acetamide (3)

To a cold (-4 °C) mixture of 70% nitric acid (18.2 mL) and concentrated sulfuric acid (18.2 mL), compound 2 (10 g, 0.05 mol) was added in small portions.
The mixture was stirred at 0 °C for 10 min and then at room temperature for further 30 min.
The acidic solution was then poured into ice-cold water.
The precipitates obtained were filtered off and washed thoroughly with ice-cold water.
Pale yellow colored desired product 3 was obtained (yield 90%, m.p. 106-108 °C).

References:

Patel, Saloni B.;Patel, Bhumika D.;Pannecouque, Christophe;Bhatt, Hardik G. [European Journal of Medicinal Chemistry,2016,vol. 117,p. 230 - 240]

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