[HYDROXY(METHANESULFONYLOXY)IODO]BENZENE synthesis
- Product Name:[HYDROXY(METHANESULFONYLOXY)IODO]BENZENE
- CAS Number:105551-42-6
- Molecular formula:C7H9IO4S
- Molecular Weight:316.11
75-75-2
629 suppliers
$10.00/5g
591-50-4
484 suppliers
$10.00/1g
105551-42-6
42 suppliers
$60.00/100mg
Yield:105551-42-6 56%
Reaction Conditions:
with 3-chloro-benzenecarboperoxoic acid in chloroform at 20; for 2 h;
Steps:
General procedure for synthesis of hypervalent iodine compounds (2a-f)
General procedure: In a round-bottom flask, iodine benzene (10.0 mmol), sulfonic acid (11.0 mmol), and chloroform (10.0 mL) were added successively and the mixture was stirred for 5 minutes at room temperature. Then m-CPBA (11.0 mmol) was put in slowly and the reaction mixture was stirred at room temperature. After the reaction, the reaction mixture was filtered, and the solid was washed with ether.
References:
Liu, Ruojuan;Wang, Junzheng;Hu, Wen;Zhang, Xiaohui;Xiong, Yan [Synthetic Communications,2018,vol. 48,# 15,p. 1957 - 1965] Location in patent:supporting information
75-75-2
629 suppliers
$10.00/5g
3240-34-4
591 suppliers
$7.00/10g
105551-42-6
42 suppliers
$60.00/100mg
75-75-2
629 suppliers
$10.00/5g
71-43-2
701 suppliers
$11.19/25ML
105551-42-6
42 suppliers
$60.00/100mg