Fialuridine synthesis
- Product Name:Fialuridine
- CAS Number:69123-98-4
- Molecular formula:C9H10FIN2O5
- Molecular Weight:372.09
97614-45-4
28 suppliers
$160.00/25mg
69123-98-4
137 suppliers
$25.00/1mg
Yield: 91.8%
Reaction Conditions:
Stage #1:5-iodo-1-(2'-deoxy-2'-fluoro-3',5'-di-O-benzoyl-β-D-arabinofuranosyl)uracil with water;sodium hydroxide in tetrahydrofuran for 4 h;
Stage #2:Acidic conditions;
Steps:
5.3.2
8.14 (14.03 mmol) 5-iodo-1-(2'-deoxy-2'-fluoro-3',5'-di-O-benzoyl-β-D-arabinofuranosyl)uracil are dissolved in 250 ml THF and mixed with 50 ml (100 mmol) 2 M sodium hydroxide solution. After 4 h the reaction is terminated. The solution is neutralised and extracted several times with acetic ester. The combined extracts are dried with magnesium sulphate. After filtration and centrifugation of the solvent, purification by column chromatography is effected (chloroform/methanol 10:1). 4.80 g (91.8%) of a colourless solid is obtained.
References:
RESprotech GmbH US2010/227834, 2010, A1 Location in patent:Page/Page column 18
69123-94-0
154 suppliers
$60.00/1 g
69123-98-4
137 suppliers
$25.00/1mg
1000210-73-0
0 suppliers
inquiry
69123-98-4
137 suppliers
$25.00/1mg
213136-12-0
24 suppliers
inquiry
69123-98-4
137 suppliers
$25.00/1mg
97614-43-2
329 suppliers
$5.00/250mg
69123-98-4
137 suppliers
$25.00/1mg