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ChemicalBook CAS DataBase List 2-(N,N-DIMETHYLCARBOXAMIDO)PHENYLBORONIC ACID PINACOL ESTER
956229-73-5

2-(N,N-DIMETHYLCARBOXAMIDO)PHENYLBORONIC ACID PINACOL ESTER synthesis

5synthesis methods
-

Yield:956229-73-5 82%

Reaction Conditions:

Stage #1: bis(pinacol)diboranewith 5-methyl-2-(thiophen-3-yl)pyridine;(1,5-cyclooctadiene)(methoxy)iridium(I) dimer in tetrahydrofuran at 20; for 0.0333333 h;Inert atmosphere;Glovebox;
Stage #2: N,N-dimethylbenzamide in tetrahydrofuran at 100; for 12 h;Inert atmosphere;Sealed tube;regioselective reaction;

References:

Chattopadhyay, Buddhadeb;Hassan, Mirja Md Mahamudul;Hoque, Md Emdadul [Journal of the American Chemical Society,2021,vol. 143,# 13,p. 5022 - 5037] Location in patent:supporting information

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